Organic electroluminescent material and device thereof

ABSTRACT

Provided are an organic electroluminescent material and a device thereof. The organic electroluminescent material is a metal complex comprising a ligand L a  having a structure of Formula 1. The metal complex may be used as a light-emitting material in an electroluminescent device. These new compounds may be applied to electroluminescent devices and can exhibit better performance, achieve higher device efficiency, and significantly improve the overall performance of the devices. Further provided are an electroluminescent device comprising the metal complex and a compound combination comprising the metal complex.

CROSS-REFERENCE TO RELATED APPLICATION(S)

This application claims priority to Chinese Patent Application No. CN 202110423792.3 filed on Apr. 21, 2021, the disclosure of which is incorporated herein by reference in its entirety.

TECHNICAL FIELD

The present disclosure relates to compounds for organic electronic devices such as organic light-emitting devices. More particularly, the present disclosure relates to a metal complex including a ligand L_(a) having a structure of Formula 1 and an electroluminescent device and compound combination including the metal complex.

BACKGROUND

Organic electronic devices include, but are not limited to, the following types: organic light-emitting diodes (OLEDs), organic field-effect transistors (O-FETs), organic light-emitting transistors (OLETs), organic photovoltaic devices (OPVs), dye-sensitized solar cells (DSSCs), organic optical detectors, organic photoreceptors, organic field-quench devices (OFQDs), light-emitting electrochemical cells (LECs), organic laser diodes and organic plasmon emitting devices.

In 1987, Tang and Van Slyke of Eastman Kodak reported a bilayer organic electroluminescent device, which includes an arylamine hole transporting layer and a tris-8-hydroxyquinolato-aluminum layer as the electron and emitting layer (Applied Physics Letters, 1987, 51 (12): 913-915). Once a bias is applied to the device, green light was emitted from the device. This device laid the foundation for the development of modern organic light-emitting diodes (OLEDs). State-of-the-art OLEDs may include multiple layers such as charge injection and transporting layers, charge and exciton blocking layers, and one or multiple emissive layers between the cathode and anode. Since the OLED is a self-emitting solid state device, it offers tremendous potential for display and lighting applications. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on flexible substrates.

The OLED can be categorized as three different types according to its emitting mechanism. The OLED invented by Tang and van Slyke is a fluorescent OLED. It only utilizes singlet emission. The triplets generated in the device are wasted through nonradiative decay channels. Therefore, the internal quantum efficiency (IQE) of the fluorescent OLED is only 25%. This limitation hindered the commercialization of OLED. In 1997, Forrest and Thompson reported phosphorescent OLED, which uses triplet emission from heavy metal containing complexes as the emitter. As a result, both singlet and triplets can be harvested, achieving 100% IQE. The discovery and development of phosphorescent OLED contributed directly to the commercialization of active-matrix OLED (AMOLED) due to its high efficiency. Recently, Adachi achieved high efficiency through thermally activated delayed fluorescence (TADF) of organic compounds. These emitters have small singlet-triplet gap that makes the transition from triplet back to singlet possible. In the TADF device, the triplet excitons can go through reverse intersystem crossing to generate singlet excitons, resulting in high IQE.

OLEDs can also be classified as small molecule and polymer OLEDs according to the forms of the materials used. A small molecule refers to any organic or organometallic material that is not a polymer. The molecular weight of the small molecule can be large as long as it has well defined structure. Dendrimers with well-defined structures are considered as small molecules. Polymer OLEDs include conjugated polymers and non-conjugated polymers with pendant emitting groups. Small molecule OLED can become the polymer OLED if post polymerization occurred during the fabrication process.

There are various methods for OLED fabrication. Small molecule OLEDs are generally fabricated by vacuum thermal evaporation. Polymer OLEDs are fabricated by solution process such as spin-coating, inkjet printing, and slit printing. If the material can be dissolved or dispersed in a solvent, the small molecule OLED can also be produced by solution process.

The emitting color of the OLED can be achieved by emitter structural design. An OLED may include one emitting layer or a plurality of emitting layers to achieve desired spectrum. In the case of green, yellow, and red OLEDs, phosphorescent emitters have successfully reached commercialization. Blue phosphorescent device still suffers from non-saturated blue color, short device lifetime, and high operating voltage. Commercial full-color OLED displays normally adopt a hybrid strategy, using fluorescent blue and phosphorescent yellow, or red and green. At present, efficiency roll-off of phosphorescent OLEDs at high brightness remains a problem. In addition, it is desirable to have more saturated emitting color, higher efficiency, and longer device lifetime.

US2013119354A1 discloses an iridium complex having the following structure:

wherein R₁ to R₄ are selected from hydrogen, deuterium, alkyl, cycloalkyl, aryl or heteroaryl. The effect of R₁ including cyano substituted has neither disclosed nor taught.

US20200287144A1 discloses a metal complex including ligands having the following structures:

and wherein X₁ is selected from silyl or germanyl. An iridium complex is further disclosed which has a structure represented by the following general formula:

The disclosed specific structures include

This application focuses on the effect of substituent containing silyl or germanyl at a particular position of the metal complex on device performance and has neither disclosed nor taught an effect of a CN-containing substituent introduced at a particular position of the metal complex on the device performance.

SUMMARY

The present disclosure aims to provide a series of metal complexes each comprising a ligand L_(a) having a structure of Formula 1 to solve at least part of the above-mentioned problems.

According to an embodiment of the present disclosure, disclosed is a metal complex comprising a metal M and a ligand L_(a) coordinated to the metal M, wherein the metal M is selected from a metal with a relative atomic mass greater than 40, and the ligand L_(a) has a structure represented by Formula 1:

wherein in Formula 1,

Cy is, at each occurrence identically or differently, selected from a substituted or unsubstituted aromatic ring having 6 to 24 ring atoms, a substituted or unsubstituted heteroaromatic ring having 5 to 24 ring atoms or a combination thereof;

X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′, wherein when two R′ are present at the same time, the two R′ are the same or different;

X₁ to X₄ are, at each occurrence identically or differently, selected from C, CR_(x) or N, and at least one of X₁ to X₄ is C and joined to the Cy;

X₅ to X₇ are, at each occurrence identically or differently, selected from CR_(x) or N;

X₈ is selected from C;

X₁, X₂, X₃ or X₄ is joined to the metal M by a metal-carbon bond or a metal-nitrogen bond;

R′ is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof; and

adjacent substituents R′, R_(w), R_(x) can be optionally joined to form a ring.

According to another embodiment of the present disclosure, further disclosed is an electroluminescent device, the electroluminescent device comprises:

an anode,

a cathode, and

an organic layer disposed between the anode and the cathode, wherein the organic layer comprises the metal complex in the preceding embodiment.

According to another embodiment of the present disclosure, further disclosed is a compound combination comprising the metal complex in the preceding embodiment.

The series of metal complexes each comprising the ligand L_(a) having the structure of Formula 1, disclosed by the present disclosure, may be used as light-emitting materials in electroluminescent devices. These novel metal complexes may be applied to the electroluminescent devices and can improve device efficiency and significantly improve the overall performance of the devices.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a schematic diagram of an electroluminescent device that may contain a metal complex and a compound combination disclosed herein.

FIG. 2 is a schematic diagram of another electroluminescent device that may contain a metal complex and a compound combination disclosed herein.

DETAILED DESCRIPTION

OLEDs can be fabricated on various types of substrates such as glass, plastic, and metal foil. FIG. 1 schematically shows an organic light-emitting device 100 without limitation. The figures are not necessarily drawn to scale. Some of the layers in the figures can also be omitted as needed. Device 100 may include a substrate 101, an anode 110, a hole injection layer 120, a hole transport layer 130, an electron blocking layer 140, an emissive layer 150, a hole blocking layer 160, an electron transport layer 170, an electron injection layer 180 and a cathode 190. Device 100 may be fabricated by depositing the layers described in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, the contents of which are incorporated by reference herein in its entirety.

More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference herein in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference herein in its entirety. Examples of host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference herein in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference herein in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference herein in their entireties, disclose examples of cathodes including composite cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers are described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference herein in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference herein in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference herein in its entirety.

The layered structure described above is provided by way of non-limiting examples. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely. It may also include other layers not specifically described. Within each layer, a single material or a mixture of multiple materials can be used to achieve optimum performance. Any functional layer may include several sublayers. For example, the emissive layer may have two layers of different emitting materials to achieve desired emission spectrum.

In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may include a single layer or multiple layers.

An OLED can be encapsulated by a barrier layer. FIG. 2 schematically shows an organic light emitting device 200 without limitation. FIG. 2 differs from FIG. 1 in that the organic light emitting device include a barrier layer 102, which is above the cathode 190, to protect it from harmful species from the environment such as moisture and oxygen. Any material that can provide the barrier function can be used as the barrier layer such as glass or organic-inorganic hybrid layers. The barrier layer should be placed directly or indirectly outside of the OLED device. Multilayer thin film encapsulation was described in U.S. Pat. No. 7,968,146, which is incorporated by reference herein in its entirety.

Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Some examples of such consumer products include flat panel displays, monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, smart phones, tablets, phablets, wearable devices, smart watches, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles displays, and vehicle tail lights.

The materials and structures described herein may be used in other organic electronic devices listed above.

As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from the substrate. There may be other layers between the first and second layers, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.

As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.

It is believed that the internal quantum efficiency (IQE) of fluorescent OLEDs can exceed the 25% spin statistics limit through delayed fluorescence. As used herein, there are two types of delayed fluorescence, i.e. P-type delayed fluorescence and E-type delayed fluorescence. P-type delayed fluorescence is generated from triplet-triplet annihilation (TTA).

On the other hand, E-type delayed fluorescence does not rely on the collision of two triplets, but rather on the transition between the triplet states and the singlet excited states. Compounds that are capable of generating E-type delayed fluorescence are required to have very small singlet-triplet gaps to convert between energy states. Thermal energy can activate the transition from the triplet state back to the singlet state. This type of delayed fluorescence is also known as thermally activated delayed fluorescence (TADF). A distinctive feature of TADF is that the delayed component increases as temperature rises. If the reverse intersystem crossing (RISC) rate is fast enough to minimize the non-radiative decay from the triplet state, the fraction of back populated singlet excited states can potentially reach 75%. The total singlet fraction can be 100%, far exceeding 25% of the spin statistics limit for electrically generated excitons.

E-type delayed fluorescence characteristics can be found in an exciplex system or in a single compound. Without being bound by theory, it is believed that E-type delayed fluorescence requires the luminescent material to have a small singlet-triplet energy gap (Δ_(ES-T)). Organic, non-metal containing, donor-acceptor luminescent materials may be able to achieve this. The emission in these materials is generally characterized as a donor-acceptor charge-transfer (CT) type emission. The spatial separation of the HOMO and LUMO in these donor-acceptor type compounds generally results in small Δ_(ES-T). These states may involve CT states. Generally, donor-acceptor luminescent materials are constructed by connecting an electron donor moiety such as amino- or carbazole-derivatives and an electron acceptor moiety such as N-containing six-membered aromatic rings.

Definition of Terms of Substituents

Halogen or halide—as used herein includes fluorine, chlorine, bromine, and iodine.

Alkyl—as used herein includes both straight and branched chain alkyl groups. Alkyl may be alkyl having 1 to 20 carbon atoms, preferably alkyl having 1 to 12 carbon atoms, and more preferably alkyl having 1 to 6 carbon atoms. Examples of alkyl groups include a methyl group, an ethyl group, a propyl group, an isopropyl group, a n-butyl group, an s-butyl group, an isobutyl group, a t-butyl group, an n-pentyl group, an n-hexyl group, an n-heptyl group, an n-octyl group, an n-nonyl group, an n-decyl group, an n-undecyl group, an n-dodecyl group, an n-tridecyl group, an n-tetradecyl group, an n-pentadecyl group, an n-hexadecyl group, an n-heptadecyl group, an n-octadecyl group, a neopentyl group, a 1-methylpentyl group, a 2-methylpentyl group, a 1-pentylhexyl group, a 1-butylpentyl group, a 1-heptyloctyl group, and a 3-methylpentyl group. Of the above, preferred are a methyl group, an ethyl group, a propyl group, an isopropyl group, a n-butyl group, an s-butyl group, an isobutyl group, a t-butyl group, an n-pentyl group, a neopentyl group, and an n-hexyl group. Additionally, the alkyl group may be optionally substituted.

Cycloalkyl—as used herein includes cyclic alkyl groups. The cycloalkyl groups may be those having 3 to 20 ring carbon atoms, preferably those having 4 to 10 carbon atoms. Examples of cycloalkyl include cyclobutyl, cyclopentyl, cyclohexyl, 4-methylcyclohexyl, 4,4-dimethylcylcohexyl, 1-adamantyl, 2-adamantyl, 1-norbornyl, 2-norbornyl, and the like. Of the above, preferred are cyclopentyl, cyclohexyl, 4-methylcyclohexyl, and 4,4-dimethylcylcohexyl. Additionally, the cycloalkyl group may be optionally substituted.

Heteroalkyl—as used herein, includes a group formed by replacing one or more carbons in an alkyl chain with a hetero-atom(s) selected from the group consisting of a nitrogen atom, an oxygen atom, a sulfur atom, a selenium atom, a phosphorus atom, a silicon atom, a germanium atom, and a boron atom. Heteroalkyl may be those having 1 to 20 carbon atoms, preferably those having 1 to 10 carbon atoms, and more preferably those having 1 to 6 carbon atoms. Examples of heteroalkyl include methoxymethyl, ethoxymethyl, ethoxyethyl, methylthiomethyl, ethylthiomethyl, ethylthioethyl, methoxymethoxymethyl, ethoxymethoxymethyl, ethoxyethoxyethyl, hydroxymethyl, hydroxyethyl, hydroxypropyl, mercaptomethyl, mercaptoethyl, mercaptopropyl, aminomethyl, aminoethyl, aminopropyl, dimethylaminomethyl, trimethylgermanylmethyl, trimethylgermanylethyl, trimethylgermanylisopropyl, dimethylethylgermanylmethyl, dimethylisopropylgermanylmethyl, tert-butylmethylgermanylmethyl, triethylgermanylmethyl, triethylgermanylethyl, triisopropylgermanylmethyl, triisopropylgermanylethyl, trimethylsilylmethyl, trimethylsilylethyl, trimethylsilylisopropyl, triisopropylsilylmethyl, and triisopropylsilylethyl. Additionally, the heteroalkyl group may be optionally substituted.

Alkenyl—as used herein includes straight chain, branched chain, and cyclic alkene groups. Alkenyl may be those having 2 to 20 carbon atoms, preferably those having 2 to 10 carbon atoms. Examples of alkenyl include vinyl, 1-propenyl group, 1-butenyl, 2-butenyl, 3-butenyl, 1,3-butandienyl, 1-methylvinyl, styryl, 2,2-diphenylvinyl, 1,2-diphenylvinyl, 1-methylallyl, 1,1-dimethylallyl, 2-methylallyl, 1-phenylallyl, 2-phenylallyl, 3-phenylallyl, 3,3-diphenylallyl, 1,2-dimethylallyl, 1-phenyl-1-butenyl, 3-phenyl-1-butenyl, cyclopentenyl, cyclopentadienyl, cyclohexenyl, cycloheptenyl, cycloheptatrienyl, cyclooctenyl, cyclooctatetraenyl, and norbornenyl. Additionally, the alkenyl group may be optionally substituted.

Alkynyl—as used herein includes straight chain alkynyl groups. Alkynyl may be those having 2 to 20 carbon atoms, preferably those having 2 to 10 carbon atoms. Examples of alkynyl groups include ethynyl, propynyl, propargyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-pentynyl, 2-pentynyl, 3,3-dimethyl-1-butynyl, 3-ethyl-3-methyl-1-pentynyl, 3,3-diisopropyl-1-pentynyl, phenylethynyl, phenylpropynyl, etc. Of the above, preferred are ethynyl, propynyl, propargyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-pentynyl, and phenylethynyl. Additionally, the alkynyl group may be optionally substituted.

Aryl or an aromatic group—as used herein includes non-condensed and condensed systems. Aryl may be those having 6 to 30 carbon atoms, preferably those having 6 to 20 carbon atoms, and more preferably those having 6 to 12 carbon atoms. Examples of aryl groups include phenyl, biphenyl, terphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, terphenyl, triphenylene, fluorene, and naphthalene. Examples of non-condensed aryl groups include phenyl, biphenyl-2-yl, biphenyl-3-yl, biphenyl-4-yl, p-terphenyl-4-yl, p-terphenyl-3-yl, p-terphenyl-2-yl, m-terphenyl-4-yl, m-terphenyl-3-yl, m-terphenyl-2-yl, o-tolyl, m-tolyl, p-tolyl, p-(2-phenylpropyl)phenyl, 4′-methylbiphenylyl, 4″-t-butyl-p-terphenyl-4-yl, o-cumenyl, m-cumenyl, p-cumenyl, 2,3-xylyl, 3,4-xylyl, 2,5-xylyl, mesityl, and m-quarterphenyl. Additionally, the aryl group may be optionally substituted.

Heterocyclic groups or heterocycle—as used herein include non-aromatic cyclic groups. Non-aromatic heterocyclic groups include saturated heterocyclic groups having 3 to 20 ring atoms and unsaturated non-aromatic heterocyclic groups having 3 to 20 ring atoms, where at least one ring atom is selected from the group consisting of a nitrogen atom, an oxygen atom, a sulfur atom, a selenium atom, a silicon atom, a phosphorus atom, a germanium atom, and a boron atom. Preferred non-aromatic heterocyclic groups are those having 3 to 7 ring atoms, each of which includes at least one hetero-atom such as nitrogen, oxygen, silicon, or sulfur. Examples of non-aromatic heterocyclic groups include oxiranyl, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl, dioxolanyl, dioxanyl, aziridinyl, dihydropyrrolyl, tetrahydropyrrolyl, piperidinyl, oxazolidinyl, morpholinyl, piperazinyl, oxepinyl, thiepinyl, azepinyl, and tetrahydrosilolyl. Additionally, the heterocyclic group may be optionally substituted.

Heteroaryl—as used herein, includes non-condensed and condensed hetero-aromatic groups having 1 to 5 hetero-atoms, where at least one hetero-atom is selected from the group consisting of a nitrogen atom, an oxygen atom, a sulfur atom, a selenium atom, a silicon atom, a phosphorus atom, a germanium atom, and a boron atom. A hetero-aromatic group is also referred to as heteroaryl. Heteroaryl may be those having 3 to 30 carbon atoms, preferably those having 3 to 20 carbon atoms, and more preferably those having 3 to 12 carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridoindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.

Alkoxy—as used herein, is represented by —O-alkyl, —O-cycloalkyl, —O-heteroalkyl, or —O-heterocyclic group. Examples and preferred examples of alkyl, cycloalkyl, heteroalkyl, and heterocyclic groups are the same as those described above. Alkoxy groups may be those having 1 to 20 carbon atoms, preferably those having 1 to 6 carbon atoms. Examples of alkoxy groups include methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, tetrahydrofuranyloxy, tetrahydropyranyloxy, methoxypropyloxy, ethoxyethyloxy, methoxymethyloxy, and ethoxymethyloxy. Additionally, the alkoxy group may be optionally substituted.

Aryloxy—as used herein, is represented by —O-aryl or —O-heteroaryl. Examples and preferred examples of aryl and heteroaryl are the same as those described above. Aryloxy groups may be those having 6 to 30 carbon atoms, preferably those having 6 to 20 carbon atoms. Examples of aryloxy groups include phenoxy and biphenyloxy. Additionally, the aryloxy group may be optionally substituted.

Alkylthio—as used herein, is represented by —S-alkyl, —S-cycloalkyl, —S-heteroalkyl or —S-heterocyclic group. Examples and preferred examples of alkyl, cycloalkyl, heteroalkyl and heterocyclic groups are the same as those described above. Alkylthio groups may be those having 1 to 20 carbon atoms, preferably those having 1 to 6 carbon atoms. Examples of alkylthio groups include methylthio, ethylthio, propylthio, butylthio, pentylthio, hexylthio, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, tetrahydrofurylthio, tetrahydropyranylthio, methylthiopropylthio, ethylthioethylthio, methylthiomethylthio and ethylthiomethylthio. Additionally, the alkylthio group may be optionally substituted.

Arylthio—as used herein, is represented by —S-aryl or —S-heteroaryl. Examples and preferred examples of aryl and heteroaryl are the same as those described above. Arylthio groups may be those having 6 to 30 carbon atoms, preferably those having 6 to 20 carbon atoms. Examples of arylthio groups include phenylthio, biphenylthio and naphthylthio. Additionally, the arylthio group may be optionally substituted.

Arylalkyl—as used herein, contemplates alkyl substituted with an aryl group. Arylalkyl may be those having 7 to 30 carbon atoms, preferably those having 7 to 20 carbon atoms, and more preferably those having 7 to 13 carbon atoms. Examples of arylalkyl groups include benzyl, 1-phenylethyl, 2-phenylethyl, 1-phenylisopropyl, 2-phenylisopropyl, phenyl-t-butyl, alpha-naphthylmethyl, 1-alpha-naphthylethyl, 2-alpha-naphthylethyl, 1-alpha-naphthylisopropyl, 2-alpha-naphthylisopropyl, beta-naphthylmethyl, 1-beta-naphthylethyl, 2-beta-naphthylethyl, 1-beta-naphthylisopropyl, 2-beta-naphthylisopropyl, p-methylbenzyl, m-methylbenzyl, o-methylbenzyl, p-chlorobenzyl, m-chlorobenzyl, o-chlorobenzyl, p-bromobenzyl, m-bromobenzyl, o-bromobenzyl, p-iodobenzyl, m-iodobenzyl, o-iodobenzyl, p-hydroxybenzyl, m-hydroxybenzyl, o-hydroxybenzyl, p-aminobenzyl, m-aminobenzyl, o-aminobenzyl, p-nitrobenzyl, m-nitrobenzyl, o-nitrobenzyl, p-cyanobenzyl, m-cyanobenzyl, o-cyanobenzyl, 1-hydroxy-2-phenylisopropyl, and 1-chloro-2-phenylisopropyl. Of the above, preferred are benzyl, p-cyanobenzyl, m-cyanobenzyl, o-cyanobenzyl, 1-phenylethyl, 2-phenylethyl, 1-phenylisopropyl, and 2-phenylisopropyl. Additionally, the arylalkyl group may be optionally substituted.

Alkylsilyl—as used herein, contemplates a silyl group substituted with an alkyl group. Alkylsilyl groups may be those having 3 to 20 carbon atoms, preferably those having 3 to 10 carbon atoms. Examples of alkylsilyl groups include trimethylsilyl, triethylsilyl, methyldiethylsilyl, ethyldimethylsilyl, tripropylsilyl, tributylsilyl, triisopropylsilyl, methyldiisopropylsilyl, dimethylisopropylsilyl, tri-t-butylsilyl, triisobutylsilyl, dimethyl t-butylsilyl, and methyldi-t-butylsilyl. Additionally, the alkylsilyl group may be optionally substituted.

Arylsilyl—as used herein, contemplates a silyl group substituted with an aryl group. Arylsilyl groups may be those having 6 to 30 carbon atoms, preferably those having 8 to 20 carbon atoms. Examples of arylsilyl groups include triphenylsilyl, phenyldibiphenylylsilyl, diphenylbiphenylsilyl, phenyldiethylsilyl, diphenylethylsilyl, phenyldimethylsilyl, diphenylmethylsilyl, phenyldiisopropylsilyl, diphenylisopropylsilyl, diphenylbutylsilyl, diphenylisobutylsilyl, diphenyl t-butylsilyl. Additionally, the arylsilyl group may be optionally substituted.

Alkylgermanyl—as used herein contemplates germanyl substituted with an alkyl group. The alkylgermanyl may be those having 3 to 20 carbon atoms, preferably those having 3 to 10 carbon atoms. Examples of alkylgermanyl include trimethylgermanyl, triethylgermanyl, methyldiethylgermanyl, ethyldimethylgermanyl, tripropylgermanyl, tributylgermanyl, triisopropylgermanyl, methyldiisopropylgermanyl, dimethylisopropylgermanyl, tri-t-butylgermanyl, triisobutylgermanyl, dimethyl-t-butylgermanyl, and methyldi-t-butylgermanyl. Additionally, the alkylgermanyl may be optionally substituted.

Arylgermanyl—as used herein contemplates germanyl substituted with at least one aryl group or heteroaryl group. Arylgermanyl may be those having 6 to 30 carbon atoms, preferably those having 8 to 20 carbon atoms. Examples of arylgermanyl include triphenylgermanyl, phenyldibiphenylylgermanyl, diphenylbiphenylgermanyl, phenyldiethylgermanyl, diphenylethylgermanyl, phenyldimethylgermanyl, diphenylmethylgermanyl, phenyldiisopropylgermanyl, diphenylisopropylgermanyl, diphenylbutylgermanyl, diphenylisobutylgermanyl, and diphenyl-t-butylgermanyl. Additionally, the arylgermanyl may be optionally substituted.

The term “aza” in azadibenzofuran, azadibenzothiophene, etc. means that one or more of C—H groups in the respective aromatic fragment are replaced by a nitrogen atom. For example, azatriphenylene encompasses dibenzo[f,h]quinoxaline, dibenzo[f,h]quinoline and other analogs with two or more nitrogens in the ring system. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.

In the present disclosure, unless otherwise defined, when any term of the group consisting of substituted alkyl, substituted cycloalkyl, substituted heteroalkyl, substituted heterocyclic group, substituted arylalkyl, substituted alkoxy, substituted aryloxy, substituted alkenyl, substituted alkynyl, substituted aryl, substituted heteroaryl, substituted alkylsilyl, substituted arylsilyl, substituted alkylgermanyl, substituted arylgermanyl, substituted amino, substituted acyl, substituted carbonyl, a substituted carboxylic acid group, a substituted ester group, substituted sulfinyl, substituted sulfonyl, and substituted phosphino is used, it means that any group of alkyl, cycloalkyl, heteroalkyl, heterocyclic group, arylalkyl, alkoxy, aryloxy, alkenyl, alkynyl, aryl, heteroaryl, alkylsilyl, arylsilyl, amino, acyl, carbonyl, a carboxylic acid group, an ester group, sulfinyl, sulfonyl, and phosphino may be substituted with one or more moieties selected from the group consisting of deuterium, halogen, unsubstituted alkyl having 1 to 20 carbon atoms, unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, unsubstituted heteroalkyl having 1 to 20 carbon atoms, an unsubstituted heterocyclic group having 3 to 20 ring atoms, unsubstituted arylalkyl having 7 to 30 carbon atoms, unsubstituted alkoxy having 1 to 20 carbon atoms, unsubstituted aryloxy having 6 to 30 carbon atoms, unsubstituted alkenyl having 2 to 20 carbon atoms, unsubstituted alkynyl having 2 to 20 carbon atoms, unsubstituted aryl having 6 to 30 carbon atoms, unsubstituted heteroaryl having 3 to 30 carbon atoms, unsubstituted alkylsilyl having 3 to 20 carbon atoms, unsubstituted arylsilyl group having 6 to 20 carbon atoms, unsubstituted alkylgermanyl having 3 to 20 carbon atoms, unsubstituted arylgermanyl having 6 to 20 carbon atoms, unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof.

It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or an attached fragment are considered to be equivalent.

In the compounds mentioned in the present disclosure, hydrogen atoms may be partially or fully replaced by deuterium. Other atoms such as carbon and nitrogen may also be replaced by their other stable isotopes. The replacement by other stable isotopes in the compounds may be preferred due to its enhancements of device efficiency and stability.

In the compounds mentioned in the present disclosure, multiple substitution refers to a range that includes a di-substitution, up to the maximum available substitution. When substitution in the compounds mentioned in the present disclosure represents multiple substitution (including di-, tri-, and tetra-substitutions etc.), that means the substituent may exist at a plurality of available substitution positions on its linking structure, the substituents present at a plurality of available substitution positions may have the same structure or different structures.

In the compounds mentioned in the present disclosure, adjacent substituents in the compounds cannot be joined to form a ring unless otherwise explicitly defined, for example, adjacent substituents can be optionally joined to form a ring. In the compounds mentioned in the present disclosure, the expression that adjacent substituents can be optionally joined to form a ring includes a case where adjacent substituents may be joined to form a ring and a case where adjacent substituents are not joined to form a ring. When adjacent substituents can be optionally joined to form a ring, the ring formed may be monocyclic or polycyclic (including spirocyclic, endocyclic, fusedcyclic, and etc.), as well as alicyclic, heteroalicyclic, aromatic, or heteroaromatic. In such expression, adjacent substituents may refer to substituents bonded to the same atom, substituents bonded to carbon atoms which are directly bonded to each other, or substituents bonded to carbon atoms which are more distant from each other. Preferably, adjacent substituents refer to substituents bonded to the same carbon atom and substituents bonded to carbon atoms which are directly bonded to each other.

The expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that two substituents bonded to the same carbon atom are joined to each other via a chemical bond to form a ring, which can be exemplified by the following formula:

The expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that two substituents bonded to carbon atoms which are directly bonded to each other are joined to each other via a chemical bond to form a ring, which can be exemplified by the following formula:

The expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that two substituents bonded to a further distant carbon atom are joined to each other via a chemical bond to form a ring, which can be exemplified by the following formula:

Furthermore, the expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that, in the case where one of the two substituents bonded to carbon atoms which are directly bonded to each other represents hydrogen, the second substituent is bonded at a position at which the hydrogen atom is bonded, thereby forming a ring. This is exemplified by the following formula:

According to an embodiment of the present disclosure, disclosed is a metal complex comprising a metal M and a ligand L_(a) coordinated to the metal M, wherein the metal M is selected from a metal with a relative atomic mass greater than 40, and the ligand L_(a) has a structure represented by Formula 1:

wherein in Formula 1,

Cy is, at each occurrence identically or differently, selected from a substituted or unsubstituted aromatic ring having 6 to 24 ring atoms, a substituted or unsubstituted heteroaromatic ring having 5 to 24 ring atoms or a combination thereof;

X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′, wherein when two R′ are present at the same time, the two R′ are the same or different;

X₁ to X₄ are, at each occurrence identically or differently, selected from C, CR_(x) or N, and at least one of X₁ to X₄ is C and joined to the Cy;

X₅ to X₇ are, at each occurrence identically or differently, selected from CR_(x) or N;

X₈ is selected from C;

X₁, X₂, X₃ or X₄ is joined to the metal M by a metal-carbon bond or a metal-nitrogen bond;

R′ is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof; and

adjacent substituents R′, R_(w), R_(x) can be optionally joined to form a ring.

In the present disclosure, the expression that “adjacent substituents R′, R_(w), R_(x) can be optionally joined to form a ring” is intended to mean that any one or more of groups of adjacent substituents, such as two substituents R′, two substituents R_(x), substituents R′ and R_(x) and substituents R_(w) and R_(x), can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, Cy is any structure selected from the group consisting of:

wherein

R represents, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution; and when multiple R are present at the same time in any structure, the multiple R are the same or different;

R is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

two adjacent substituents R can be optionally joined to form a ring; and

wherein “#” represents a position where Cy is joined to the metal M, and

represents a position where Cy is joined to X₁, X₂, X₃ or X₄.

In the present disclosure, the expression that “two adjacent substituents R can be optionally joined to form a ring” is intended to mean that any one or more of groups of any two adjacent substituents R can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, L_(a) is, at each occurrence identically or differently, selected from the group consisting of:

wherein

X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′; wherein when two R′ are present at the same time, the two R′ are the same or different;

R and R_(x) represent, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution;

R and R′ are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof; and

adjacent substituents R, R′, R_(w) and R_(x) can be optionally joined to form a ring.

In the present disclosure, the expression that “adjacent substituents R, R′, R_(w) and R_(x) can be optionally joined to form a ring” is intended to mean that any one or more of groups of adjacent substituents, such as two substituents R, two substituents R′, two substituents R_(x), substituents R′ and R_(x) and substituents R_(w) and R_(x), can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, the metal complex has a general formula of M(L_(a))_(m)(L_(b))_(n)(L_(c))_(q);

wherein

M is, at each occurrence identically or differently, selected from the group consisting of Cu, Ag, Au, Ru, Rh, Pd, Os, Ir and Pt;

L_(a), L_(b) and L_(c) are a first ligand, a second ligand and a third ligand coordinated to the metal M, respectively, and L_(c) is the same as or different from L_(a) or L_(b); wherein L_(a), L_(b) and L_(c) can be optionally joined to form a multidentate ligand; for example, any two of L_(a), L_(b) and L_(c) may be joined to form a tetradentate ligand; in another example, L_(a), L_(b) and L_(c) may be joined to each other to form a hexadentate ligand; in another example, none of L_(a), L_(b) and L_(c) are joined so that no multidentate ligand is formed;

m is selected from 1, 2 or 3, n is selected from 0, 1 or 2, q is selected from 0, 1 or 2, and m+n+q equals an oxidation state of the metal M; wherein when m is greater than or equal to 2, multiple L_(a) are the same or different; when n is equal to 2, two L_(b) are the same or different; when q is equal to 2, two L_(c) are the same or different;

L_(b) and L_(c) are, at each occurrence identically or differently, selected from a structure represented by any one of the group consisting of:

wherein

R_(a) and R_(b) represent, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution;

X_(b) is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, NR_(N1) and CR_(C1)R_(C2);

R_(a), R_(b), R_(c), R_(N1), R_(C1) and R_(C2) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; and

adjacent substituents R_(a), R_(b), R_(c), R_(N1), R_(C1) and R_(C2) can be optionally joined to form a ring.

In the present disclosure, the expression that “adjacent substituents R_(a), R_(b), R_(c), R_(N1), R_(C1) and R_(C2) can be optionally joined to form a ring” is intended to mean that any one or more of groups of adjacent substituents, such as two substituents R_(a), two substituents R_(b), substituents R_(a) and R_(b), substituents R_(a) and R_(e), substituents R_(b) and R_(e), substituents R_(a) and R_(N1), substituents R_(b) and R_(N1), substituents R_(a) and R_(C1), substituents R_(a) and R_(C2), substituents R_(b) and R_(C1), substituents R_(b) and R_(C2) and substituents R_(C1) and R_(C2), can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, wherein, the metal M is, at each occurrence identically or differently, selected from the group consisting of Cu, Ag, Au, Ru, Rh, Pd, Os, Ir and Pt.

According to an embodiment of the present disclosure, wherein, the metal M is, at each occurrence identically or differently, selected from Pt or Ir.

According to an embodiment of the present disclosure, wherein, the metal complex Ir(L_(a))_(m)(L_(b))_(3-m) has a structure represented by Formula 3:

wherein

X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′, wherein when two R′ are present at the same time, the two R′ are the same or different;

m is selected from 1, 2 or 3; when m is selected from 1, two L_(b) are the same or different; when m is selected from 2 or 3, multiple L_(a) are the same or different;

Y₁ to Y₄ are, at each occurrence identically or differently, selected from CR_(y) or N;

X₃ to X₇ are, at each occurrence identically or differently, selected from CR_(x) or N;

X₈ is selected from C;

R′, R_(y) and R₁ to R₈ are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof;

adjacent substituents R′, R_(w), R_(x) and R_(y) can be optionally joined to form a ring; and

adjacent substituents R₁ to R₈ can be optionally joined to form a ring.

In the present disclosure, the expression that “adjacent substituents R′, R_(w), R_(x) and R_(y) can be optionally joined to form a ring” is intended to mean that any one or at least two of groups of adjacent substituents, such as two substituents R′, two substituents R_(x), two substituents R_(y) and substituents R_(w) and R_(x), can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

In the present disclosure, the expression that “adjacent substituents R₁ to R₈ can be optionally joined to form a ring” is intended to mean that any one or at least two of groups of adjacent substituents, such as adjacent substituents R₁ and R₂, adjacent substituents R₃ and R₂, adjacent substituents R₃ and R₄, adjacent substituents R₅ and R₄, adjacent substituents R₅ and R₆, adjacent substituents R₇ and R₆ and adjacent substituents R₇ and R₈, can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, wherein, the metal complex Ir(L_(a))_(m)(L_(b))_(3-m) has a structure represented by Formula 3A:

wherein

m is selected from 1, 2 or 3; when m is selected from 1, two L_(b) are the same or different; when m is selected from 2 or 3, multiple L_(a) are the same or different;

X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′, wherein when two R′ are present at the same time, the two R′ are the same or different;

R_(x) and R_(y) represent, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution;

R′, R_(y) and R₁ to R₈ are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof;

adjacent substituents R′, R_(w), R_(x) and R_(y) can be optionally joined to form a ring; and

adjacent substituents R₁ to R₈ can be optionally joined to form a ring.

According to an embodiment of the present disclosure, wherein, X is selected from O or S.

According to an embodiment of the present disclosure, wherein, X is O.

According to an embodiment of the present disclosure, wherein, X₁ to X₇ are, at each occurrence identically or differently, selected from C or CR_(x).

According to an embodiment of the present disclosure, wherein, at least one of X₁ to X₇ is N, for example, one of X₁ to X₇ is N or two of X₁ to X₇ are N.

According to an embodiment of the present disclosure, in Formula 3, X₃ to X₇ are, at each occurrence identically or differently, selected from CR_(x).

According to an embodiment of the present disclosure, in Formula 3, at least one of X₃ to X₇ is N, for example, one of X₃ to X₇ is N or two of X₃ to X₇ are N.

According to an embodiment of the present disclosure, wherein, Y₁ to Y₄ are, at each occurrence identically or differently, selected from CR_(y).

According to an embodiment of the present disclosure, wherein, at least one of Y₁ to Y₄ is N, for example, one of Y₁ to Y₄ is N or two of Y₁ to Y₄ are N.

According to an embodiment of the present disclosure, wherein, at least one of X₃ to X₇ is selected from CR_(x), and the R_(x) is cyano.

According to an embodiment of the present disclosure, at least one of X₅ to X₇ is selected from CR_(x), and the R_(x) is cyano.

According to an embodiment of the present disclosure, wherein, X₇ is CR_(x), and the R_(x) is cyano.

According to an embodiment of the present disclosure, wherein, R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, cyano and combinations thereof.

According to an embodiment of the present disclosure, wherein, R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, substituted or unsubstituted aryl having 6 to 12 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 12 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 6 carbon atoms, cyano and combinations thereof.

According to an embodiment of the present disclosure, wherein, R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, cyano and combinations thereof.

According to an embodiment of the present disclosure, wherein, at least one R_(x) is selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, substituted or unsubstituted aryl having 6 to 12 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 12 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 6 carbon atoms, cyano and combinations thereof.

According to an embodiment of the present disclosure, wherein, at least one R_(x) is selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, substituted or unsubstituted aryl having 6 to 12 carbon atoms, cyano and combinations thereof.

According to an embodiment of the present disclosure, wherein, R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, R_(w) is, at each occurrence identically or differently, selected from arylene having 6 to 30 carbon atoms.

According to an embodiment of the present disclosure, wherein, R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted arylene having 6 to 12 carbon atoms and substituted or unsubstituted heteroarylene having 3 to 12 carbon atoms.

According to an embodiment of the present disclosure, wherein, R_(w) is, at each occurrence identically or differently, selected from the group consisting of: cyclopentylene, cyclohexylene, phenylene, pyridylene, pyrimidinylene, triazinylene, naphthylene, phenanthrylene, anthrylene, fluorenylidene, silafluorenylidene, quinolylene, isoquinolylene, dithiophenylene, difurylene, benzofurylene, benzothienylene, dibenzofurylene, dibenzothienylene, triphenylenylene, carbazolylene, azacarbazolylene, azafluorenylidene, azasilafluorenylidene, azadibenzofurylene, azadibenzothienylene and combinations thereof; optionally, hydrogens in the above groups are partially or fully deuterated.

According to an embodiment of the present disclosure, wherein, R_(w) is, at each occurrence identically or differently, selected from the group consisting of A-1 to A-194, wherein the specific structures of A-1 to A-194 are referred to claim 10.

According to an embodiment of the present disclosure, wherein, hydrogens in A-1 to A-194 can be partially or fully deuterated, and the specific structures of A-1 to A-194 are referred to claim 10.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, R_(y) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, R_(y) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, fluorine, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, substituted or unsubstituted aryl having 6 to 12 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 11 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 6 carbon atoms, cyano and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3, R_(y) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, fluorine, substituted or unsubstituted alkyl having 1 to 6 carbon atoms and substituted or unsubstituted aryl having 6 to 12 carbon atoms.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, R_(y) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, t-butyl, cyclopentyl, cyclohexyl, deuterated methyl, deuterated ethyl, deuterated propyl, deuterated isopropyl, deuterated n-butyl, deuterated isobutyl, deuterated t-butyl, deuterated cyclopentyl, deuterated cyclohexyl, phenyl, pyridyl, trimethylsilyl and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, at least one R_(y) is selected from the group consisting of: deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, at least one or at least two of R₅ to R₈ are selected from substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms or a combination thereof, and the total number of carbon atoms in all of R₅ to R₈ is at least 4.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, at least one or at least two of R₆ and R₇ are selected from substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms or a combination thereof, and the total number of carbon atoms in both of R₆ and R₇ is at least 4.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, R₇ is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, R₇ is selected from substituted or unsubstituted alkyl having 4 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 4 to 20 ring carbon atoms or a combination thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, at least one, at least two, at least three or all of R₂, R₃, R₆ and R₇ are selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, at least one, at least two, at least three or all of R₂, R₃, R₆ and R₇ are selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, in Formula 3 and Formula 3A, at least one, at least two, at least three or all of R₂, R₃, R₆ and R₇ are selected from the group consisting of: deuterium, methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, t-butyl, cyclopentyl, cyclohexyl, neopentyl, t-pentyl and combinations thereof.

According to an embodiment of the present disclosure, wherein, R′ is selected from substituted or unsubstituted alkyl having 1 to 20 carbon atoms or substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms.

According to an embodiment of the present disclosure, wherein, R′ is selected from methyl or deuterated methyl.

According to an embodiment of the present disclosure, wherein, L_(a) is, at each occurrence identically or differently, selected from the group consisting of L_(a1) to L_(a770), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14.

According to an embodiment of the present disclosure, wherein, hydrogens in the structures of L_(a1) to L_(a770) can be partially or fully deuterated, wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14.

According to an embodiment of the present disclosure, wherein, L_(b) is, at each occurrence identically or differently, selected from the group consisting of L_(b1) to L_(b329), wherein the specific structures of L_(b1) to L_(b329) are referred to claim 15.

According to an embodiment of the present disclosure, wherein, hydrogens in the structures of L_(b1) to L_(b329) can be partially or fully deuterated, wherein the specific structures of L_(b1) to L_(b329) are referred to claim 15.

According to an embodiment of the present disclosure, wherein, L_(c) is, at each occurrence identically or differently, selected from the group consisting of L_(c1) to L_(c360), wherein the specific structures of L_(c1) to L_(c360) are referred to claim 16.

According to an embodiment of the present disclosure, wherein, the metal complex has a structure of Ir(L_(a))₂(L_(b)), wherein L_(a) is, at each occurrence identically or differently, selected from any one or any two of the group consisting of L_(a1) to L_(a770) and L_(b) is selected from any one of the group consisting of L_(b1) to L_(b329), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14 and the specific structures of L_(b1) to L_(b329) are referred to claim 15.

According to an embodiment of the present disclosure, wherein, the metal complex has a structure of Ir(L_(a))(L_(b))₂, wherein L_(a) is, at each occurrence identically or differently, selected from any one of the group consisting of L_(a1) to L_(a770) and L_(b) is selected from any one or any two of the group consisting of L_(b1) to L_(b329), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14 and the specific structures of L_(b1) to L_(b329) are referred to claim 15.

According to one embodiment of the present disclosure, wherein, the metal complex has a structure of Ir(L_(a))₃, wherein L_(a) is, at each occurrence identically or differently, selected from any one or any two or any three of the group consisting of L_(a1) to L_(a770), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14.

According to an embodiment of the present disclosure, wherein, the metal complex has a structure of Ir(L_(a))₂(L_(c)), wherein L_(a) is, at each occurrence identically or differently, selected from any one or any two of the group consisting of L_(a1) to L_(a770) and L_(c) is selected from any one of the group consisting of L_(c1) to L_(c360), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14 and the specific structures of L_(c1) to L_(c360) are referred to claim 16.

According to an embodiment of the present disclosure, wherein, the metal complex has a structure of Ir(L_(a))(L_(c))₂, wherein L_(a) is, at each occurrence identically or differently, selected from any one of the group consisting of L_(a1) to L_(a770) and L_(c) is selected from any one or any two of the group consisting of L_(c1) to L_(c360), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14 and the specific structures of L_(c1) to L_(c360) are referred to claim 16.

According to an embodiment of the present disclosure, wherein, the metal complex has a structure of Ir(L_(a))(L_(b))(L_(c)), wherein L_(a) is, at each occurrence identically or differently, selected from any one of the group consisting of L_(a1) to L_(a770), L_(b) is selected from any one of the group consisting of L_(b1) to L_(b329), and L_(c) is selected from any one of the group consisting of L_(c1) to L_(c360), wherein the specific structures of L_(a1) to L_(a770) are referred to claim 14, the specific structures of L_(b1) to L_(b329) are referred to claim 15, and the specific structures of L_(c1) to L_(c360) are referred to claim 16.

According to an embodiment of the present disclosure, wherein, the metal complex is selected from the group consisting of Metal Complex 1 to Metal Complex 1578, wherein the specific structures of Metal Complex 1 to Metal Complex 1578 are referred to claim 17.

According to an embodiment of the present disclosure, wherein, hydrogens in the structures of Metal Complex 1 to Metal Complex 1578 can be partially or fully deuterated, wherein the specific structures of Metal Complex 1 to Metal Complex 1578 are referred to claim 17.

According to an embodiment of the present disclosure, disclosed is an electroluminescent device. The electroluminescent device comprises:

an anode,

a cathode, and

an organic layer disposed between the anode and the cathode, wherein the organic layer comprises the metal complex in any one of the preceding embodiments.

According to an embodiment of the present disclosure, in the electroluminescent device, the organic layer comprising the metal complex is a light-emitting layer.

According to an embodiment of the present disclosure, wherein the electroluminescent device emits green light.

According to an embodiment of the present disclosure, wherein the electroluminescent device emits white light.

According to an embodiment of the present disclosure, in the electroluminescent device, the light-emitting layer comprises a first host compound.

According to an embodiment of the present disclosure, in the electroluminescent device, the light-emitting layer comprises a first host compound and a second host compound.

According to an embodiment of the present disclosure, in the electroluminescent device, the first host compound and/or the second host compound comprise at least one chemical group selected from the group consisting of: benzene, pyridine, pyrimidine, triazine, carbazole, azacarbazole, indolocarbazole, dibenzothiophene, aza-dibenzothiophene, dibenzofuran, azadibenzofuran, dibenzoselenophene, triphenylene, azatriphenylene, fluorene, silafluorene, naphthalene, quinoline, isoquinoline, quinazoline, quinoxaline, phenanthrene, azaphenanthrene and combinations thereof.

According to an embodiment of the present disclosure, wherein, the first host compound has a structure represented by Formula 4:

wherein

E₁ to E₆ are, at each occurrence identically or differently, selected from C, CR_(e) or N, at least two of E₁ to E₆ are N, and at least one of E₁ to E₆ is C and joined to Formula A;

wherein

Q is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, N, NR′″, CR′″R′″, SiR′″R′″, GeR′″R′″ and R′″C═CR′″; when two R′″ are present at the same time, the two R′″ may be the same or different;

p is 0 or 1; r is 0 or 1;

when Q is selected from N, p is 0 and r is 1;

when Q is selected from the group consisting of O, S, Se, NR′″, CR′″R′″, SiR′″R′″, GeR′″R′″ and R′″C═CR′″, p is 1 and r is 0;

L is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 20 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 20 carbon atoms or a combination thereof;

Q₁ to Q₈ are, at each occurrence identically or differently, selected from C, CR_(q) or N;

R_(e), R′″ and R_(q) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

“*” represents a position where Formula A is joined to Formula 4; and

adjacent substituents R_(e), R′″, R_(q) can be optionally joined to form a ring.

In the present disclosure, the expression that “adjacent substituents R_(e), R′″, R_(q) can be optionally joined to form a ring” is intended to mean that any one or at least two of groups of adjacent substituents, such as two substituents R_(e), two substituents R′″, two substituents R_(q) and substituents R′″ and R_(q), can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, wherein, Q is, at each occurrence identically or differently, selected from O, S, N or NR′″.

According to an embodiment of the present disclosure, wherein, E₁ to E₆ are, at each occurrence identically or differently, selected from C, CR_(e) or N, three of E₁ to E₆ are N, at least one of E₁ to E₆ is CR_(e), and R_(e) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein, E₁ to E₆ are, at each occurrence identically or differently, selected from C, CR_(e) or N, three of E₁ to E₆ are N, at least one of E₁ to E₆ is CR_(e), and R_(e) is, at each occurrence identically or differently, selected from substituted or unsubstituted phenyl, substituted or unsubstituted biphenyl, substituted or unsubstituted terphenyl, substituted or unsubstituted naphthyl, substituted or unsubstituted phenanthryl, substituted or unsubstituted triphenylene, substituted or unsubstituted fluorenyl, substituted or unsubstituted dibenzofuryl, substituted or unsubstituted dibenzothienyl, substituted or unsubstituted carbazolyl or a combination thereof.

According to an embodiment of the present disclosure, wherein R_(e) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein R_(e) is, at each occurrence identically or differently, selected from substituted or unsubstituted phenyl, substituted or unsubstituted biphenyl, substituted or unsubstituted terphenyl, substituted or unsubstituted naphthyl, substituted or unsubstituted phenanthryl, substituted or unsubstituted triphenylene, substituted or unsubstituted fluorenyl, substituted or unsubstituted dibenzofuryl, substituted or unsubstituted dibenzothienyl, substituted or unsubstituted carbazolyl or a combination thereof.

According to an embodiment of the present disclosure, wherein, at least one or at least two of Q₁ to Q₈ are selected from CR_(q), and R_(q) is selected from substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 5 to 30 carbon atoms or a combination thereof.

According to an embodiment of the present disclosure, wherein, at least one or at least two of Q₁ to Q₈ are selected from CR_(q), and R_(q) is selected from substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl, substituted or unsubstituted biphenyl, substituted or unsubstituted terphenyl, substituted or unsubstituted pyridyl or a combination thereof.

According to an embodiment of the present disclosure, wherein R′″ is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof.

According to an embodiment of the present disclosure, wherein R′″ is, at each occurrence identically or differently, selected from substituted or unsubstituted phenyl, substituted or unsubstituted biphenyl, substituted or unsubstituted terphenyl, substituted or unsubstituted naphthyl, substituted or unsubstituted phenanthryl, substituted or unsubstituted triphenylene, substituted or unsubstituted fluorenyl, substituted or unsubstituted dibenzofuryl, substituted or unsubstituted dibenzothienyl, substituted or unsubstituted carbazolyl or a combination thereof.

According to an embodiment of the present disclosure, wherein L is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted arylene having 6 to 20 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 20 carbon atoms or a combination thereof.

According to an embodiment of the present disclosure, wherein L is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted phenylene, substituted or unsubstituted biphenylene, substituted or unsubstituted carbazolylene, substituted or unsubstituted dibenzofurylene, substituted or unsubstituted dibenzothienylene or substituted or unsubstituted fluorenylidene.

According to an embodiment of the present disclosure, L is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted phenylene or substituted or unsubstituted biphenylene.

According to an embodiment of the present disclosure, the first host compound is selected from the group consisting of H-1 to H-243, wherein the specific structures of H-1 to H-243 are referred to claim 23.

According to an embodiment of the present disclosure, in the electroluminescent device, the second host compound has a structure represented by Formula 5:

wherein

L_(x) is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 20 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 20 carbon atoms or a combination thereof;

V is, at each occurrence identically or differently, selected from C, CR_(v) or N, and at least one of V is C and joined to L_(x);

U is, at each occurrence identically or differently, selected from C, CR_(u) or N, and at least one of U is C and joined to L_(x);

R_(v) and R_(u) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

Ar₆ is, at each occurrence identically or differently, selected from substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms or a combination thereof; and

adjacent substituents R_(v) and R_(u) can be optionally joined to form a ring.

In this embodiment, the expression that “adjacent substituents R_(v) and R_(u) can be optionally joined to form a ring” is intended to mean that any one or more of groups of adjacent substituents, such as two substituents R_(v), two substituents R_(u), and substituents R_(v) and R_(u), can be joined to form a ring. Obviously, it is possible that none of these substituents are joined to form a ring.

According to an embodiment of the present disclosure, in the electroluminescent device, the second host compound has a structure represented by one of Formula 5-a to Formula 5-j:

wherein

L_(x) is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 20 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 20 carbon atoms or a combination thereof;

V is, at each occurrence identically or differently, selected from CR_(v) or N;

U is, at each occurrence identically or differently, selected from CR_(u) or N;

R_(v) and R_(u) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof;

Ar₆ is, at each occurrence identically or differently, selected from substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms or a combination thereof; and

adjacent substituents R_(v) and R_(u) can be optionally joined to form a ring.

According to an embodiment of the present disclosure, the second host compound is selected from the group consisting of X-1 to X-150, wherein the specific structures of X-1 to X-150 are referred to claim 25.

According to an embodiment of the present disclosure, in the electroluminescent device, the metal complex is doped in the first host compound and the second host compound, and the weight of the metal complex accounts for 1% to 30% of the total weight of the light-emitting layer.

According to an embodiment of the present disclosure, in the electroluminescent device, the metal complex is doped in the first host compound and the second host compound, and the weight of the metal complex accounts for 3% to 13% of the total weight of the light-emitting layer.

According to another embodiment of the present disclosure, disclosed is a compound combination comprising the metal complex in any one of the preceding embodiments.

Combination with Other Materials

The materials described in the present disclosure for a particular layer in an organic light emitting device can be used in combination with various other materials present in the device. The combinations of these materials are described in more detail in U.S. Pat. App. No. 20160359122 at paragraphs 0132-0161, which is incorporated by reference herein in its entirety. The materials described or referred to the disclosure are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a variety of other materials present in the device. For example, dopants disclosed herein may be used in combination with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The combination of these materials is described in detail in paragraphs 0080-0101 of U.S. Pat. App. No. 20150349273, which is incorporated by reference herein in its entirety. The materials described or referred to the disclosure are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

In the embodiments of material synthesis, all reactions were performed under nitrogen protection unless otherwise stated. All reaction solvents were anhydrous and used as received from commercial sources. Synthetic products were structurally confirmed and tested for properties using one or more conventional equipment in the art (including, but not limited to, nuclear magnetic resonance instrument produced by BRUKER, liquid chromatograph produced by SHIMADZU, liquid chromatograph-mass spectrometry produced by SHIMADZU, gas chromatograph-mass spectrometry produced by SHIMADZU, differential Scanning calorimeters produced by SHIMADZU, fluorescence spectrophotometer produced by SHANGHAI LENGGUANG TECH., electrochemical workstation produced by WUHAN CORRTEST, and sublimation apparatus produced by ANHUI BEQ, etc.) by methods well known to the persons skilled in the art. In the embodiments of the device, the characteristics of the device were also tested using conventional equipment in the art (including, but not limited to, evaporator produced by ANGSTROM ENGINEERING, optical testing system produced by SUZHOU FATAR, life testing system produced by SUZHOU FATAR, and ellipsometer produced by BEIJING ELLITOP, etc.) by methods well known to the persons skilled in the art. As the persons skilled in the art are aware of the above-mentioned equipment use, test methods and other related contents, the inherent data of the sample can be obtained with certainty and without influence, so the above related contents are not further described in this patent.

MATERIAL SYNTHESIS EXAMPLE

The method for preparing a compound in the present disclosure is not limited herein. Typically, the following compounds are used as examples without limitations, and synthesis routes and preparation methods thereof are described below.

Synthesis Example 1: Synthesis of Metal Complex 493

Step 1:

5-Methyl-2-phenylpyridine (10.0 g, 59.2 mmol), iridium trichloride trihydrate (5.0 g, 14.2 mmol), 300 mL of 2-ethoxyethanol and 100 mL of water were sequentially added to a dry 500 mL round-bottom flask, purged with nitrogen three times, and heated and stirred for 24 h at 130° C. under nitrogen protection. The solution was cooled, filtered, washed three times with methanol and n-hexane respectively, and pumped to dryness to obtain 7.5 g of Intermediate 1 as a yellow solid (with a yield of 97%).

Step 2:

Intermediate 1 (7.5 g, 6.8 mmol), 250 mL of anhydrous dichloromethane, 10 mL of methanol and silver trifluoromethanesulfonate (3.8 g, 14.8 mmol) were sequentially added to a dry 500 mL round-bottom flask, purged with nitrogen three times, and stirred overnight at room temperature under nitrogen protection. The solution was filtered through Celite and washed twice with dichloromethane. The organic phases below were collected and concentrated under reduced pressure to obtain 9.2 g of Intermediate 2 (with a yield of 93%).

Step 3:

Intermediate 3 (3.0 g, 8.6 mmol), Intermediate 2 (3.7 g, 5.8 mmol), 50 mL of 2-ethoxyethanol and 50 mL of N,N-dimethylformamide were sequentially added to a dry 250 mL round-bottom flask, purged with nitrogen three times, and heated at 100° C. for 96 h under nitrogen protection. The reaction was cooled, filtered through Celite, and washed twice with methanol and n-hexane respectively. Yellow solids on the Celite were dissolved in dichloromethane. The organic phases were collected, concentrated under reduced pressure, and purified through column chromatography to obtain Metal Complex 493 as a yellow solid (2.20 g with a yield of 43.4%). The product was confirmed as the target product with a molecular weight of 874.2.

Synthesis Example 2: Synthesis of Metal Complex 735

Step 1:

Intermediate 4 (1.5 g, 4.0 mmol), Intermediate 2 (2.1 g, 2.9 mmol), 50 mL of 2-ethoxyethanol and 50 mL of N,N-dimethylformamide were sequentially added to a dry 250 mL round-bottom flask, purged with nitrogen three times, and heated at 100° C. for 96 h under nitrogen protection. The reaction was cooled, filtered through Celite, and washed twice with methanol and n-hexane respectively. Yellow solids on the Celite were dissolved in dichloromethane. The organic phases were collected, concentrated under reduced pressure, and purified through column chromatography to obtain Metal Complex 735 as a yellow solid (1.1 g with a yield of 42.6%). The product was confirmed as the target product with a molecular weight of 899.2.

Synthesis Example 3: Synthesis of Metal Complex 975

Step 1:

5-T-butyl-2-phenylpyridine (13.2 g, 62.9 mmol), iridium trichloride trihydrate (5.5 g, 15.7 mmol), 300 mL of 2-ethoxyethanol and 100 mL of water were sequentially added to a dry 500 mL round-bottom flask, purged with nitrogen three times, and heated and stirred for 24 h at 130° C. under nitrogen protection. The solution was cooled, filtered, washed three times with methanol and n-hexane respectively, and pumped to dryness to obtain 9.7 g of Intermediate 5 (with a yield of 97%).

Step 2:

Intermediate 5 (9.7 g, 7.7 mmol), 250 mL of anhydrous dichloromethane, 10 mL of methanol and silver trifluoromethanesulfonate (4.3 g, 16.7 mmol) were sequentially added to a dry 500 mL round-bottom flask, purged with nitrogen three times, and stirred overnight at room temperature under nitrogen protection. The solution was filtered through Celite and washed twice with dichloromethane. The organic phases below were collected and concentrated under reduced pressure to obtain 13.2 g of Intermediate 6 as a yellow solid (with a yield of 93%).

Step 3:

Intermediate 3 (1.2 g, 3.5 mmol), Intermediate 6 (2.0 g, 2.5 mmol), 50 mL of 2-ethoxyethanol and 50 mL of N,N-dimethylformamide were sequentially added to a dry 250 mL round-bottom flask, purged with nitrogen three times, and heated at 100° C. for 96 h under nitrogen protection. The reaction was cooled, filtered through Celite, and washed twice with methanol and n-hexane respectively. Yellow solids on the Celite were dissolved in dichloromethane. The organic phases were collected, concentrated under reduced pressure, and purified through column chromatography to obtain Metal Complex 975 as a yellow solid (1.3 g with a yield of 54.3%). The product was confirmed as the target product with a molecular weight of 958.3.

Synthesis Example 4: Synthesis of Metal Complex 1192

Step 1:

Intermediate 7 (1.5 g, 4.0 mmol), Intermediate 6 (2.2 g, 2.7 mmol), 50 mL of 2-ethoxyethanol and 50 mL of N,N-dimethylformamide were sequentially added to a dry 250 mL round-bottom flask, purged with nitrogen three times, and heated at 100° C. for 96 h under nitrogen protection. The reaction was cooled, filtered through Celite, and washed twice with methanol and n-hexane respectively. Yellow solids on the Celite were dissolved in dichloromethane. The organic phases were collected, concentrated under reduced pressure, and purified through column chromatography to obtain Metal Complex 1192 as a yellow solid (1.3 g with a yield of 50.0%). The product was confirmed as the target product with a molecular weight of 983.3.

Those skilled in the art will appreciate that the above preparation methods are merely exemplary. Those skilled in the art can obtain other compound structures of the present disclosure through the modifications of the preparation methods.

Device Example 1-1

First, a glass substrate having an indium tin oxide (ITO) anode with a thickness of 80 nm was cleaned and then treated with oxygen plasma and UV ozone. After the treatment, the substrate was dried in a glovebox to remove moisture. Then, the substrate was mounted on a substrate holder and placed in a vacuum chamber. Organic layers specified below were sequentially deposited through vacuum thermal evaporation on the ITO anode at a rate of 0.2 to 2 Angstroms per second and a vacuum degree of about 10⁻⁸ torr. Compound HI was used as a hole injection layer (HIL). Compound HT was used as a hole transporting layer (HTL). Compound H1 was used as an electron blocking layer (EBL). Metal Complex 493 of the present disclosure was doped in Compound H1 and Compound H2 as a dopant, and the resulting mixture was deposited for use as an emissive layer (EML). On the EML, Compound HB was used as a hole blocking layer (HBL). On the HBL, Compound ET and 8-hydroxyquinolinolato-lithium (Liq) were co-deposited for use as an electron transporting layer (ETL). Finally, 8-hydroxyquinolinolato-lithium (Liq) was deposited as an electron injection layer with a thickness of 1 nm and Al was deposited as a cathode with a thickness of 120 nm. The device was transferred back to the glovebox and encapsulated with a glass lid to complete the device.

Device Comparative Example 1-1

The implementation in Device Comparative Example 1-1 was the same as that in Device Example 1-1, except that in the EML, Metal Complex 493 of the present disclosure was replaced with Compound GD1.

Device Comparative Example 1-2

The implementation in Device Comparative Example 1-2 was the same as that in Device Example 1-1, except that in the EML, Metal Complex 493 of the present disclosure was replaced with Compound GD2.

Detailed structures and thicknesses of layers of the devices are shown in the following table. A layer using more than one material is obtained by doping different compounds at their weight ratio as recorded.

TABLE 1 Device structures in Example 1-1 and Comparative Examples 1-1 and 1-2 Device ID HIL HTL EBL EML HBL ETL Example 1-1 Compound Compound Compound Compound Compound Compound HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Metal (50 Å) (350 Å) Complex 493(63:31:6) (400 Å) Comparative Compound Compound Compound Compound Compound Compound Example 1-1 HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Compound (50 Å) (350 Å) GDI (63:31:6) (400 Å) Comparative Compound Compound Compound Compound Compound Compound Example 1-2 HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Compound (50 Å) (350 Å) GD2 (63:31:6) (400 Å)

The structures of the materials used in the devices are shown as follows:

Current-voltage-luminance (IVL) characteristics of the devices were measured. The CIE data, maximum emission wavelength λ_(max), voltage (V), current efficiency (CE) and power efficiency (PE) of each device were measured at 1000 cd/m². Data about external quantum efficiency (EQE) was measured at a constant current of 15 mA/cm². The data was recorded and shown in Table 2.

TABLE 2 Device data of Examples 1-1 and Comparative Examples 1-1 and 1-2 λ_(max) Voltage CE PE EQE Device ID CIE (x, y) (nm) (V) (cd/A) (lm/W) (%) Example 1-1 (0.348, 0.626) 530 2.67 104 123 24.81 Comparative (0.372, 0.611) 538 2.76 104 119 22.53 Example 1-1 Comparative (0.352, 0.623) 528 2.84 95 105 22.36 Example 1-2

Table 2 shows the device performance of the metal complex of the present disclosure and the comparative compounds. Example 1-1 differs from Comparative Example 1-1 only in that a substituent containing cyano is located at a different position of the ligand L_(a) of the metal complex. Compared with Comparative Example 1-1, Example 1-1 has a slightly reduced driving voltage, slightly improved PE and EQE significantly improved by 10.1%. Example 1-1 differs from Comparative Example 1-2 only in that whether a substituent at position X₈ of the ligand L_(a) of the metal complex contains cyano. Compared with Comparative Example 1-2, Example 1-1 has a device voltage reduced by 0.17 V and CE, PE and EQE that are improved by 9.5%, 17.1% and 11.0%, respectively.

The above data indicates that the metal complex of the present disclosure comprising a substituent containing cyano at a particular position of L_(a) has significantly better device efficiency and performance than the metal complexes in the comparative examples and can significantly improve the overall performance of the device.

Device Example 2-1

The implementation in Device Example 2-1 was the same as that in Device Example 1-1, except that in the EML, Metal Complex 493 of the present disclosure was replaced with Metal Complex 975 of the present disclosure.

Device Example 2-2

The implementation in Device Example 2-2 was the same as that in Device Example 1-1, except that in the EML, Metal Complex 493 of the present disclosure was replaced with Metal Complex 1192 of the present disclosure.

Device Comparative Example 2-1

The implementation in Device Comparative Example 2-1 was the same as that in Device Example 1-1, except that in the EL, Metal Complex 493 of the present disclosure was replaced with Compound GD3.

Device Comparative Example 2-2

The implementation in Device Comparative Example 2-2 was the same as that in Device Example 1-1, except that in the EL, Metal Complex 493 of the present disclosure was replaced with Compound GD4.

Detailed structures and thicknesses of layers of the devices are shown in the following table. A layer using more than one material is obtained by doping different compounds at their weight ratio as recorded.

TABLE 3 Device structures in Examples 2-1 and 2-2 and Comparative Examples 2-1 and 2-2 Device ID HIL HTL EBL EML HBL ETL Example 2-1 Compound Compound Compound Compound Compound Compound HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Metal (50 Å) (350 Å) Complex 975 (63:31:6) (400 Å) Example 2-2 Compound Compound Compound Compound Compound Compound HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Metal (50 Å) (350 Å) Complex 1192 (63:31:6) (400 Å) Comparative Compound Compound Compound Compound Compound Compound Example 2-1 HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Compound (50 Å) (350 Å) GD3 (63:31:6) (400 Å) Comparative Compound Compound Compound Compound Compound Compound Example 2-2 HI HT H1 H1:Compound HB ET:Liq (40:60) (100 Å) (350 Å) (50 Å) H2:Compound (50 Å) (350 Å) GD4 (63:31:6) (400 Å)

The structures of the new materials used in the devices are shown as follows:

IVL characteristics of the devices were measured. The CIE data, maximum emission wavelength λ_(max), voltage (V), current efficiency (CE), power efficiency (PE) and external quantum efficiency (EQE) of each device were measured at 1000 cd/m². The data was recorded and shown in Table 4.

TABLE 4 Device data of Examples 2-1 and 2-2 and Comparative Examples 2-1 and 2-2 λ_(max) Voltage CE PE EQE Device ID CIE (x, y) (nm) (V) (cd/A) (lm/W) (%) Example 2-1 (0.351, 0.625) 531 2.69 109 127 28.07 Comparative (0.353, 0.623) 531 3.11 94 95 24.33 Example 2-1 Example 2-2 (0.361, 0.622) 537 2.59 112 136 28.33 Comparative (0.342, 0.635) 531 2.70 104 121 26.21 Example 2-2

Table 4 shows the device performance of the metal complexes of the present disclosure and the comparative compounds. Example 2-1 differs from Comparative Example 2-1 only in that whether the substituent at position X₈ of the ligand L_(a) of the metal complex contains cyano. Example 2-2 differs from Comparative Example 2-2 only in that whether the substituent at position X₈ of the ligand L_(a) of the metal complex contains cyano. Compared with Comparative Example 2-1, Example 2-1 has a driving voltage reduced by 0.42 V and CE, PE and EQE that are significantly improved by 15.9%, 33.7% and 15.4%, respectively. Compared with Comparative Example 2-2, Example 2-2 has a driving voltage reduced by 0.11 V, CE and PE that are both improved by about 5%, and EQE improved by 8.1%.

The above data indicates that the metal complex of the present disclosure comprising a substituent containing cyano at a particular position of L_(a) has significantly better device efficiency and performance than the metal complexes in the comparative examples and can significantly improve the overall performance of the device.

As can be seen from the examples and comparative examples discussed above, the metal complex of the present disclosure comprising the substituent containing cyano at position X₈ of the ligand L_(a) can significantly improve device performance compared with the metal complexes in the comparative examples. The observed advantages of the compounds of the present disclosure are completely unexpected, which is impossible to predict even for a person skilled in the art.

It should be understood that various embodiments described herein are merely examples and not intended to limit the scope of the present disclosure. Therefore, it is apparent to the persons skilled in the art that the present disclosure as claimed may include variations from specific embodiments and preferred embodiments described herein. Many of materials and structures described herein may be substituted with other materials and structures without departing from the spirit of the present disclosure. It should be understood that various theories as to why the present disclosure works are not intended to be limitative. 

What is claimed is:
 1. A metal complex, comprising a metal M and a ligand L_(a) coordinated to the metal M, wherein the metal M is selected from a metal with a relative atomic mass greater than 40, and the ligand L_(a) has a structure represented by Formula 1:

wherein in Formula 1, Cy is, at each occurrence identically or differently, selected from a substituted or unsubstituted aromatic ring having 6 to 24 ring atoms, a substituted or unsubstituted heteroaromatic ring having 5 to 24 ring atoms or a combination thereof; X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′, wherein when two R′ are present at the same time, the two R′ are the same or different; X₁ to X₄ are, at each occurrence identically or differently, selected from C, CR_(x) or N, and at least one of X₁ to X₄ is C and joined to the Cy; X₅ to X₇ are, at each occurrence identically or differently, selected from CR_(x) or N; X₈ is selected from C; X₁, X₂, X₃ or X₄ is joined to the metal M by a metal-carbon bond or a metal-nitrogen bond; R′ is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof; and adjacent substituents R′, R_(w), R_(x) can be optionally joined to form a ring.
 2. The metal complex of claim 1, wherein Cy is any structure selected from the group consisting of:

wherein R represents, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution; and when multiple R are present at the same time in any structure, the multiple R are the same or different; R is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; two adjacent substituents R can be optionally joined to form a ring; and wherein “#” represents a position where Cy is joined to the metal M, and “┤” represents a position where Cy is joined to X₁, X₂, X₃ or X₄.
 3. The metal complex of claim 1, wherein the metal complex has a general formula of M(L_(a))_(m)(L_(b))_(n)(L_(c))_(q); wherein M is, at each occurrence identically or differently, selected from the group consisting of Cu, Ag, Au, Ru, Rh, Pd, Os, Ir and Pt; preferably, M is, at each occurrence identically or differently, selected from Pt or Ir; L_(a), L_(b) and L_(c) are a first ligand, a second ligand and a third ligand coordinated to the metal M, respectively, and L_(c) is the same as or different from L_(a) or L_(b); wherein L_(a), L_(b) and L_(c) can be optionally joined to form a multidentate ligand; m is selected from 1, 2 or 3, n is selected from 0, 1 or 2, q is selected from 0, 1 or 2, and m+n+q equals an oxidation state of the metal M; wherein when m is greater than or equal to 2, multiple L_(a) are the same or different; when n is equal to 2, two L_(b) are the same or different; when q is equal to 2, two L_(c) are the same or different; L_(a) is, at each occurrence identically or differently, selected from the group consisting of:

wherein X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′; wherein when two R′ are present at the same time, the two R′ are the same or different; R and R_(x) represent, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution; L_(b) and L_(c) are, at each occurrence identically or differently, selected from a structure represented by any one of the group consisting of:

wherein R_(a) and R_(b) represent, at each occurrence identically or differently, mono-substitution, multiple substitutions or non-substitution; X_(b) is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, NR_(N1) and CR_(C1)R_(C2); R, R′, R_(a), R_(b), R_(c), R_(N1), R_(C1) and R_(C2) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof; adjacent substituents R, R′, R_(w) and R_(x) can be optionally joined to form a ring; and adjacent substituents R_(a), R_(b), R_(c), R_(N1), R_(C1), R_(C2) can be optionally joined to form a ring.
 4. The metal complex of claim 1, wherein the metal complex Ir(L_(a))_(m)(L_(b))_(3-m) has a structure represented by Formula 3:

wherein X is selected from the group consisting of O, S, Se, NR′, CR′R′, SiR′R′ and GeR′R′, wherein when two R′ are present at the same time, the two R′ are the same or different; m is selected from 1, 2 or 3; when m is selected from 1, two L_(b) are the same or different; when m is selected from 2 or 3, multiple L_(a) are the same or different; Y₁ to Y₄ are, at each occurrence identically or differently, selected from CR_(y) or N; X₃ to X₇ are, at each occurrence identically or differently, selected from CR_(x) or N; X₈ is selected from C; R′, R_(y) and R₁ to R₈ are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted alkyleneoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryleneoxy having 6 to 30 carbon atoms, substituted or unsubstituted alkylsulfanylidene having 1 to 20 carbon atoms, substituted or unsubstituted arylsulfanylidene having 6 to 30 carbon atoms, substituted or unsubstituted alkenylene having 2 to 20 carbon atoms, substituted or unsubstituted alkynylene having 2 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilylene having 3 to 20 carbon atoms, substituted or unsubstituted arylsilylene having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanylidene having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanylidene having 6 to 20 carbon atoms and combinations thereof; adjacent substituents R′, R_(w), R_(x) and R_(y) can be optionally joined to form a ring; and adjacent substituents R₁ to R₈ can be optionally joined to form a ring.
 5. The metal complex of claim 1, wherein X is selected from O or S.
 6. The metal complex of claim 4, wherein X₃ to X₇ are, at each occurrence identically or differently, selected from CR_(x); and/or Y₁ to Y₄ are, at each occurrence identically or differently, selected from CR_(y).
 7. The metal complex of claim 4, wherein at least one of X₃ to X₇ is N, and/or at least one of Y₁ to Y₄ is N.
 8. The metal complex of claim 1, wherein R_(x) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, cyano and combinations thereof; preferably, at least one R_(x) is selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, substituted or unsubstituted aryl having 6 to 12 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 12 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 6 carbon atoms, cyano and combinations thereof; more preferably, at least one R_(x) is selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 6 ring carbon atoms, substituted or unsubstituted aryl having 6 to 12 carbon atoms, cyano and combinations thereof.
 9. The metal complex of claim 1, wherein R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkylene having 1 to 20 carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylalkylene having 7 to 30 carbon atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms and combinations thereof; preferably, R_(w) is, at each occurrence identically or differently, selected from the group consisting of: substituted or unsubstituted cycloalkylene having 3 to 20 ring carbon atoms, substituted or unsubstituted heterocyclylene having 3 to 20 ring atoms, substituted or unsubstituted arylene having 6 to 30 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 30 carbon atoms and combinations thereof; more preferably, R_(w) is, at each occurrence identically or differently, selected from the group consisting of: cyclopentylene, cyclohexylene, phenylene, pyridylene, pyrimidinylene, triazinylene, naphthylene, phenanthrylene, anthrylene, fluorenylidene, silafluorenylidene, quinolylene, isoquinolylene, dithiophenylene, difurylene, benzofurylene, benzothienylene, dibenzofurylene, dibenzothienylene, triphenylenylene, carbazolylene, azacarbazolylene, azafluorenylidene, azasilafluorenylidene, azadibenzofurylene, azadibenzothienylene and combinations thereof; optionally, hydrogens in the above groups are partially or fully deuterated.
 10. The metal complex of claim 1, wherein R_(w) is, at each occurrence identically or differently, selected from the group consisting of A-1 to A-194, wherein A-1 to A-194 have the following specific structures:

and combinations thereof; optionally, hydrogens in the above groups can be partially or fully deuterated; wherein “*” represents a position where R_(w) is joined to X₈ and “#” represents a position where R_(w) is joined to “CN”.
 11. The metal complex of claim 4, wherein R_(y) is, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms and combinations thereof; preferably, at least one R_(y) is selected from the group consisting of: deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof.
 12. The metal complex of claim 4, wherein at least one or at least two of R₅ to R₈ are selected from substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms or a combination thereof, and the total number of carbon atoms in all of R₅ to R₈ is at least
 4. 13. The metal complex of claim 4, wherein at least one, at least two, at least three or all of R₂, R₃, R₆ and R₇ are selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms and combinations thereof; preferably, at least one, at least two, at least three or all of R₂, R₃, R₆ and R₇ are selected from the group consisting of: deuterium, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms and combinations thereof; more preferably, at least one, at least two, at least three or all of R₂, R₃, R₆ and R₇ are selected from the group consisting of: deuterium, methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, t-butyl, cyclopentyl, cyclohexyl, neopentyl, t-pentyl and combinations thereof; optionally, hydrogens in the above groups can be partially or fully deuterated.
 14. The metal complex of claim 1, wherein L_(a) is, at each occurrence identically or differently, selected from any one of the group consisting of:

wherein, optionally, hydrogens in the structures of L_(a1) to L_(a770) can be partially or fully deuterated.
 15. The metal complex of claim 3, wherein L_(b) is, at each occurrence identically or differently, selected from the group consisting of:

wherein, optionally, hydrogens in the structures of L_(b1) to L_(b329) can be partially or fully deuterated.
 16. The metal complex of claim 3, wherein L_(c) is, at each occurrence identically or differently, selected from the group consisting of:


17. The metal complex of claim 1, wherein the metal complex has a structure of Ir(L_(a))₂(L_(b)) or Ir(L_(a))(L_(b))₂ or Ir(L_(a))₃, wherein L_(a) is, at each occurrence identically or differently, selected from any one, any two or any three of the group consisting of L_(a1) to L_(a770), and L_(b) is selected from any one or any two of the group consisting of L_(b1) to L_(b329); or the metal complex has a structure of Ir(L_(a))₂(L_(c)) or Ir(L_(a))(L)₂, wherein L_(a) is, at each occurrence identically or differently, selected from any one or any two of the group consisting of L_(a1) to L_(a770), and L_(c) is selected from any one or any two of the group consisting of L_(c) to L_(c360); or the metal complex has a structure of Ir(L_(a))(L_(b))(L_(c)), wherein L_(a) is, at each occurrence identically or differently, selected from any one of the group consisting of L_(a1) to L_(a770), L_(b) is selected from any one of the group consisting of L_(b1) to L_(b329), and L_(c) is selected from any one of the group consisting of L_(c1) to L_(c360); preferably, the metal complex is selected from the group consisting of Metal Complex 1 to Metal Complex 1578 which are described as follows: Metal Complex 1 to Metal Complex 1488 each have a structure of Ir(L_(a))(L_(b))₂, wherein the two L_(b) have the same structure or different structures, and L_(a) and the two L_(b) respectively correspond to the structures listed in the following table: Metal Metal Complex L_(a) L_(b) L_(b) Complex L_(a) L_(b) L_(b) 1 L_(a1) L_(b1) L_(b1) 2 L_(a2) L_(b1) L_(b1) 3 L_(a3) L_(b1) L_(b1) 4 L_(a4) L_(b1) L_(b1) 5 L_(a5) L_(b1) L_(b1) 6 L_(a6) L_(b1) L_(b1) 7 L_(a7) L_(b1) L_(b1) 8 L_(a8) L_(b1) L_(b1) 9 L_(a9) L_(b1) L_(b1) 10 L_(a10) L_(b1) L_(b1) 11 L_(a11) L_(b1) L_(b1) 12 L_(a12) L_(b1) L_(b1) 13 L_(a13) L_(b1) L_(b1) 14 L_(a14) L_(b1) L_(b1) 15 L_(a15) L_(b1) L_(b1) 16 L_(a16) L_(b1) L_(b1) 17 L_(a17) L_(b1) L_(b1) 18 L_(a18) L_(b1) L_(b1) 19 L_(a19) L_(b1) L_(b1) 20 L_(a20) L_(b1) L_(b1) 21 L_(a21) L_(b1) L_(b1) 22 L_(a22) L_(b1) L_(b1) 23 L_(a23) L_(b1) L_(b1) 24 L_(a24) L_(b1) L_(b1) 27 L_(a27) L_(b1) L_(b1) 28 L_(a28) L_(b1) L_(b1) 29 L_(a29) L_(b1) L_(b1) 30 L_(a30) L_(b1) L_(b1) 31 L_(a31) L_(b1) L_(b1) 32 L_(a32) L_(b1) L_(b1) 33 L_(a33) L_(b1) L_(b1) 34 L_(a34) L_(b1) L_(b1) 35 L_(a35) L_(b1) L_(b1) 36 L_(a36) L_(b1) L_(b1) 37 L_(a37) L_(b1) L_(b1) 38 L_(a38) L_(b1) L_(b1) 39 L_(a39) L_(b1) L_(b1) 40 L_(a40) L_(b1) L_(b1) 41 L_(a41) L_(b1) L_(b1) 42 L_(a42) L_(b1) L_(b1) 43 L_(a43) L_(b1) L_(b1) 44 L_(a44) L_(b1) L_(b1) 45 L_(a45) L_(b1) L_(b1) 46 L_(a46) L_(b1) L_(b1) 47 L_(a47) L_(b1) L_(b1) 48 L_(a48) L_(b1) L_(b1) 49 L_(a49) L_(b1) L_(b1) 50 L_(a50) L_(b1) L_(b1) 51 L_(a51) L_(b1) L_(b1) 52 L_(a52) L_(b1) L_(b1) 53 L_(a53) L_(b1) L_(b1) 54 L_(a54) L_(b1) L_(b1) 55 L_(a55) L_(b1) L_(b1) 56 L_(a56) L_(b1) L_(b1) 57 L_(a57) L_(b1) L_(b1) 58 L_(a58) L_(b1) L_(b1) 59 L_(a59) L_(b1) L_(b1) 60 L_(a60) L_(b1) L_(b1) 61 L_(a61) L_(b1) L_(b1) 62 L_(a62) L_(b1) L_(b1) 63 L_(a63) L_(b1) L_(b1) 64 L_(a64) L_(b1) L_(b1) 65 L_(a65) L_(b1) L_(b1) 66 L_(a66) L_(b1) L_(b1) 67 L_(a67) L_(b1) L_(b1) 68 L_(a68) L_(b1) L_(b1) 69 L_(a69) L_(b1) L_(b1) 70 L_(a70) L_(b1) L_(b1) 71 L_(a71) L_(b1) L_(b1) 72 L_(a72) L_(b1) L_(b1) 73 L_(a73) L_(b1) L_(b1) 74 L_(a74) L_(b1) L_(b1) 75 L_(a75) L_(b1) L_(b1) 76 L_(a76) L_(b1) L_(b1) 77 L_(a77) L_(b1) L_(b1) 78 L_(a78) L_(b1) L_(b1) 79 L_(a79) L_(b1) L_(b1) 80 L_(a80) L_(b1) L_(b1) 81 L_(a81) L_(b1) L_(b1) 82 L_(a82) L_(b1) L_(b1) 83 L_(a83) L_(b1) L_(b1) 84 L_(a84) L_(b1) L_(b1) 85 L_(a85) L_(b1) L_(b1) 86 L_(a86) L_(b1) L_(b1) 87 L_(a87) L_(b1) L_(b1) 88 L_(a88) L_(b1) L_(b1) 89 L_(a89) L_(b1) L_(b1) 90 L_(a90) L_(b1) L_(b1) 91 L_(a91) L_(b1) L_(b1) 92 L_(a92) L_(b1) L_(b1) 93 L_(a93) L_(b1) L_(b1) 94 L_(a94) L_(b1) L_(b1) 95 L_(a95) L_(b1) L_(b1) 96 L_(a96) L_(b1) L_(b1) 97 L_(a97) L_(b1) L_(b1) 98 L_(a98) L_(b1) L_(b1) 99 L_(a99) L_(b1) L_(b1) 100 L_(a100) L_(b1) L_(b1) 101 L_(a101) L_(b1) L_(b1) 102 L_(a102) L_(b1) L_(b1) 103 L_(a103) L_(b1) L_(b1) 104 L_(a104) L_(b1) L_(b1) 105 L_(a105) L_(b1) L_(b1) 106 L_(a106) L_(b1) L_(b1) 107 L_(a107) L_(b1) L_(b1) 108 L_(a108) L_(b1) L_(b1) 109 L_(a109) L_(b1) L_(b1) 110 L_(a110) L_(b1) L_(b1) 111 L_(a111) L_(b1) L_(b1) 112 L_(a112) L_(b1) L_(b1) 113 L_(a113) L_(b1) L_(b1) 114 L_(a114) L_(b1) L_(b1) 115 L_(a115) L_(b1) L_(b1) 116 L_(a116) L_(b1) L_(b1) 117 L_(a117) L_(b1) L_(b1) 118 L_(a118) L_(b1) L_(b1) 119 L_(a119) L_(b1) L_(b1) 120 L_(a120) L_(b1) L_(b1) 121 L_(a121) L_(b1) L_(b1) 122 L_(a122) L_(b1) L_(b1) 123 L_(a123) L_(b1) L_(b1) 124 L_(a124) L_(b1) L_(b1) 125 L_(a125) L_(b1) L_(b1) 126 L_(a126) L_(b1) L_(b1) 127 L_(a127) L_(b1) L_(b1) 128 L_(a128) L_(b1) L_(b1) 129 L_(a129) L_(b1) L_(b1) 130 L_(a130) L_(b1) L_(b1) 131 L_(a131) L_(b1) L_(b1) 132 L_(a132) L_(b1) L_(b1) 133 L_(a133) L_(b1) L_(b1) 134 L_(a134) L_(b1) L_(b1) 135 L_(a135) L_(b1) L_(b1) 136 L_(a136) L_(b1) L_(b1) 137 L_(a137) L_(b1) L_(b1) 138 L_(a138) L_(b1) L_(b1) 139 L_(a139) L_(b1) L_(b1) 140 L_(a140) L_(b1) L_(b1) 141 L_(a141) L_(b1) L_(b1) 142 L_(a142) L_(b1) L_(b1) 143 L_(a143) L_(b1) L_(b1) 144 L_(a144) L_(b1) L_(b1) 145 L_(a145) L_(b1) L_(b1) 146 L_(a146) L_(b1) L_(b1) 147 L_(a147) L_(b1) L_(b1) 148 L_(a148) L_(b1) L_(b1) 149 L_(a149) L_(b1) L_(b1) 150 L_(a150) L_(b1) L_(b1) 151 L_(a151) L_(b1) L_(b1) 152 L_(a152) L_(b1) L_(b1) 153 L_(a153) L_(b1) L_(b1) 154 L_(a154) L_(b1) L_(b1) 155 L_(a155) L_(b1) L_(b1) 156 L_(a156) L_(b1) L_(b1) 157 L_(a157) L_(b1) L_(b1) 158 L_(a158) L_(b1) L_(b1) 159 L_(a159) L_(b1) L_(b1) 160 L_(a160) L_(b1) L_(b1) 161 L_(a161) L_(b1) L_(b1) 162 L_(a162) L_(b1) L_(b1) 163 L_(a163) L_(b1) L_(b1) 164 L_(a164) L_(b1) L_(b1) 165 L_(a165) L_(b1) L_(b1) 166 L_(a166) L_(b1) L_(b1) 167 L_(a167) L_(b1) L_(b1) 168 L_(a168) L_(b1) L_(b1) 169 L_(a169) L_(b1) L_(b1) 170 L_(a170) L_(b1) L_(b1) 171 L_(a171) L_(b1) L_(b1) 172 L_(a172) L_(b1) L_(b1) 173 L_(a173) L_(b1) L_(b1) 174 L_(a174) L_(b1) L_(b1) 175 L_(a175) L_(b1) L_(b1) 176 L_(a176) L_(b1) L_(b1) 177 L_(a177) L_(b1) L_(b1) 178 L_(a178) L_(b1) L_(b1) 179 L_(a179) L_(b1) L_(b1) 180 L_(a180) L_(b1) L_(b1) 181 L_(a181) L_(b1) L_(b1) 182 L_(a182) L_(b1) L_(b1) 183 L_(a183) L_(b1) L_(b1) 184 L_(a184) L_(b1) L_(b1) 185 L_(a185) L_(b1) L_(b1) 186 L_(a186) L_(b1) L_(b1) 187 L_(a187) L_(b1) L_(b1) 188 L_(a188) L_(b1) L_(b1) 189 L_(a189) L_(b1) L_(b1) 190 L_(a190) L_(b1) L_(b1) 191 L_(a191) L_(b1) L_(b1) 192 L_(a192) L_(b1) L_(b1) 193 L_(a193) L_(b1) L_(b1) 194 L_(a194) L_(b1) L_(b1) 195 L_(a195) L_(b1) L_(b1) 196 L_(a196) L_(b1) L_(b1) 197 L_(a197) L_(b1) L_(b1) 198 L_(a198) L_(b1) L_(b1) 199 L_(a199) L_(b1) L_(b1) 200 L_(a200) L_(b1) L_(b1) 201 L_(a201) L_(b1) L_(b1) 202 L_(a202) L_(b1) L_(b1) 203 L_(a203) L_(b1) L_(b1) 204 L_(a204) L_(b1) L_(b1) 205 L_(a205) L_(b1) L_(b1) 206 L_(a206) L_(b1) L_(b1) 207 L_(a207) L_(b1) L_(b1) 208 L_(a208) L_(b1) L_(b1) 209 L_(a209) L_(b1) L_(b1) 210 L_(a210) L_(b1) L_(b1) 211 L_(a211) L_(b1) L_(b1) 212 L_(a212) L_(b1) L_(b1) 213 L_(a213) L_(b1) L_(b1) 214 L_(a214) L_(b1) L_(b1) 225 L_(a215) L_(b1) L_(b1) 226 L_(a216) L_(b1) L_(b1) 227 L_(a217) L_(b1) L_(b1) 228 L_(a218) L_(b1) L_(b1) 229 L_(a219) L_(b1) L_(b1) 230 L_(a220) L_(b1) L_(b1) 231 L_(a221) L_(b1) L_(b1) 232 L_(a222) L_(b1) L_(b1) 233 L_(a223) L_(b1) L_(b1) 234 L_(a224) L_(b1) L_(b1) 235 L_(a225) L_(b1) L_(b1) 236 L_(a226) L_(b1) L_(b1) 237 L_(a227) L_(b1) L_(b1) 238 L_(a228) L_(b1) L_(b1) 239 L_(a229) L_(b1) L_(b1) 240 L_(a230) L_(b1) L_(b1) 241 L_(a231) L_(b1) L_(b1) 242 L_(a232) L_(b1) L_(b1) 243 L_(a233) L_(b1) L_(b1) 244 L_(a234) L_(b1) L_(b1) 245 L_(a235) L_(b1) L_(b1) 246 L_(a236) L_(b1) L_(b1) 247 L_(a237) L_(b1) L_(b1) 248 L_(a238) L_(b1) L_(b1) 249 L_(a239) L_(b1) L_(b1) 250 L_(a240) L_(b1) L_(b1) 251 L_(a241) L_(b1) L_(b1) 252 L_(a242) L_(b1) L_(b1) 253 L_(a243) L_(b1) L_(b1) 254 L_(a244) L_(b1) L_(b1) 255 L_(a245) L_(b1) L_(b1) 256 L_(a246) L_(b1) L_(b1) 257 L_(a247) L_(b1) L_(b1) 258 L_(a248) L_(b1) L_(b1) 259 L_(a249) L_(b1) L_(b1) 260 L_(a250) L_(b1) L_(b1) 261 L_(a251) L_(b1) L_(b1) 262 L_(a252) L_(b1) L_(b1) 263 L_(a253) L_(b1) L_(b1) 264 L_(a254) L_(b1) L_(b1) 265 L_(a255) L_(b1) L_(b1) 266 L_(a256) L_(b1) L_(b1) 267 L_(a257) L_(b1) L_(b1) 268 L_(a258) L_(b1) L_(b1) 269 L_(a259) L_(b1) L_(b1) 270 L_(a260) L_(b1) L_(b1) 271 L_(a261) L_(b1) L_(b1) 272 L_(a262) L_(b1) L_(b1) 273 L_(a263) L_(b1) L_(b1) 274 L_(a264) L_(b1) L_(b1) 275 L_(a265) L_(b1) L_(b1) 276 L_(a266) L_(b1) L_(b1) 277 L_(a267) L_(b1) L_(b1) 278 L_(a268) L_(b1) L_(b1) 279 L_(a269) L_(b1) L_(b1) 280 L_(a270) L_(b1) L_(b1) 281 L_(a271) L_(b1) L_(b1) 282 L_(a272) L_(b1) L_(b1) 283 L_(a273) L_(b1) L_(b1) 284 L_(a274) L_(b1) L_(b1) 285 L_(a275) L_(b1) L_(b1) 286 L_(a276) L_(b1) L_(b1) 287 L_(a277) L_(b1) L_(b1) 288 L_(a278) L_(b1) L_(b1) 289 L_(a279) L_(b1) L_(b1) 290 L_(a280) L_(b1) L_(b1) 291 L_(a281) L_(b1) L_(b1) 292 L_(a282) L_(b1) L_(b1) 293 L_(a283) L_(b1) L_(b1) 294 L_(a284) L_(b1) L_(b1) 295 L_(a285) L_(b1) L_(b1) 296 L_(a286) L_(b1) L_(b1) 297 L_(a287) L_(b1) L_(b1) 298 L_(a288) L_(b1) L_(b1) 299 L_(a289) L_(b1) L_(b1) 300 L_(a290) L_(b1) L_(b1) 301 L_(a291) L_(b1) L_(b1) 302 L_(a292) L_(b1) L_(b1) 303 L_(a293) L_(b1) L_(b1) 304 L_(a294) L_(b1) L_(b1) 305 L_(a295) L_(b1) L_(b1) 306 L_(a296) L_(b1) L_(b1) 307 L_(a297) L_(b1) L_(b1) 308 L_(a298) L_(b1) L_(b1) 309 L_(a299) L_(b1) L_(b1) 310 L_(a300) L_(b1) L_(b1) 311 L_(a301) L_(b1) L_(b1) 312 L_(a302) L_(b1) L_(b1) 313 L_(a303) L_(b1) L_(b1) 314 L_(a304) L_(b1) L_(b1) 315 L_(a305) L_(b1) L_(b1) 316 L_(a306) L_(b1) L_(b1) 317 L_(a307) L_(b1) L_(b1) 318 L_(a308) L_(b1) L_(b1) 319 L_(a309) L_(b1) L_(b1) 320 L_(a310) L_(b1) L_(b1) 321 L_(a311) L_(b1) L_(b1) 322 L_(a312) L_(b1) L_(b1) 323 L_(a313) L_(b1) L_(b1) 324 L_(a314) L_(b1) L_(b1) 325 L_(a315) L_(b1) L_(b1) 326 L_(a316) L_(b1) L_(b1) 327 L_(a317) L_(b1) L_(b1) 328 L_(a318) L_(b1) L_(b1) 329 L_(a319) L_(b1) L_(b1) 330 L_(a320) L_(b1) L_(b1) 331 L_(a321) L_(b1) L_(b1) 332 L_(a322) L_(b1) L_(b1) 333 L_(a323) L_(b1) L_(b1) 334 L_(a324) L_(b1) L_(b1) 335 L_(a325) L_(b1) L_(b1) 336 L_(a326) L_(b1) L_(b1) 337 L_(a327) L_(b1) L_(b1) 338 L_(a328) L_(b1) L_(b1) 339 L_(a329) L_(b1) L_(b1) 340 L_(a330) L_(b1) L_(b1) 341 L_(a331) L_(b1) L_(b1) 342 L_(a332) L_(b1) L_(b1) 343 L_(a333) L_(b1) L_(b1) 344 L_(a334) L_(b1) L_(b1) 345 L_(a335) L_(b1) L_(b1) 346 L_(a336) L_(b1) L_(b1) 347 L_(a337) L_(b1) L_(b1) 348 L_(a338) L_(b1) L_(b1) 349 L_(a339) L_(b1) L_(b1) 350 L_(a340) L_(b1) L_(b1) 351 L_(a341) L_(b1) L_(b1) 352 L_(a342) L_(b1) L_(b1) 353 L_(a343) L_(b1) L_(b1) 354 L_(a344) L_(b1) L_(b1) 355 L_(a345) L_(b1) L_(b1) 356 L_(a346) L_(b1) L_(b1) 357 L_(a347) L_(b1) L_(b1) 358 L_(a348) L_(b1) L_(b1) 359 L_(a349) L_(b1) L_(b1) 360 L_(a350) L_(b1) L_(b1) 361 L_(a351) L_(b1) L_(b1) 362 L_(a352) L_(b1) L_(b1) 363 L_(a353) L_(b1) L_(b1) 364 L_(a354) L_(b1) L_(b1) 365 L_(a355) L_(b1) L_(b1) 366 L_(a356) L_(b1) L_(b1) 367 L_(a357) L_(b1) L_(b1) 368 L_(a358) L_(b1) L_(b1) 369 L_(a359) L_(b1) L_(b1) 370 L_(a360) L_(b1) L_(b1) 371 L_(a361) L_(b1) L_(b1) 372 L_(a362) L_(b1) L_(b1) 373 L_(a363) L_(b1) L_(b1) 374 L_(a364) L_(b1) L_(b1) 375 L_(a365) L_(b1) L_(b1) 376 L_(a366) L_(b1) L_(b1) 377 L_(a367) L_(b1) L_(b1) 378 L_(a368) L_(b1) L_(b1) 379 L_(a369) L_(b1) L_(b1) 380 L_(a370) L_(b1) L_(b1) 381 L_(a371) L_(b1) L_(b1) 382 L_(a372) L_(b1) L_(b1) 383 L_(a373) L_(b1) L_(b1) 384 L_(a374) L_(b1) L_(b1) 385 L_(a375) L_(b1) L_(b1) 386 L_(a376) L_(b1) L_(b1) 387 L_(a377) L_(b1) L_(b1) 388 L_(a378) L_(b1) L_(b1) 389 L_(a379) L_(b1) L_(b1) 390 L_(a380) L_(b1) L_(b1) 391 L_(a381) L_(b1) L_(b1) 392 L_(a382) L_(b1) L_(b1) 393 L_(a383) L_(b1) L_(b1) 394 L_(a384) L_(b1) L_(b1) 395 L_(a385) L_(b1) L_(b1) 396 L_(a386) L_(b1) L_(b1) 397 L_(a387) L_(b1) L_(b1) 398 L_(a388) L_(b1) L_(b1) 399 L_(a389) L_(b1) L_(b1) 400 L_(a390) L_(b1) L_(b1) 401 L_(a391) L_(b1) L_(b1) 402 L_(a392) L_(b1) L_(b1) 403 L_(a393) L_(b1) L_(b1) 404 L_(a394) L_(b1) L_(b1) 405 L_(a395) L_(b1) L_(b1) 406 L_(a396) L_(b1) L_(b1) 407 L_(a397) L_(b1) L_(b1) 408 L_(a398) L_(b1) L_(b1) 409 L_(a399) L_(b1) L_(b1) 410 L_(a400) L_(b1) L_(b1) 411 L_(a401) L_(b1) L_(b1) 412 L_(a402) L_(b1) L_(b1) 413 L_(a403) L_(b1) L_(b1) 414 L_(a404) L_(b1) L_(b1) 415 L_(a405) L_(b1) L_(b1) 416 L_(a406) L_(b1) L_(b1) 417 L_(a407) L_(b1) L_(b1) 418 L_(a408) L_(b1) L_(b1) 419 L_(a409) L_(b1) L_(b1) 420 L_(a410) L_(b1) L_(b1) 421 L_(a411) L_(b1) L_(b1) 422 L_(a412) L_(b1) L_(b1) 423 L_(a413) L_(b1) L_(b1) 424 L_(a414) L_(b1) L_(b1) 425 L_(a415) L_(b1) L_(b1) 426 L_(a416) L_(b1) L_(b1) 427 L_(a417) L_(b1) L_(b1) 428 L_(a418) L_(b1) L_(b1) 429 L_(a419) L_(b1) L_(b1) 430 L_(a420) L_(b1) L_(b1) 431 L_(a421) L_(b1) L_(b1) 432 L_(a422) L_(b1) L_(b1) 433 L_(a423) L_(b1) L_(b1) 434 L_(a424) L_(b1) L_(b1) 435 L_(a425) L_(b1) L_(b1) 436 L_(a426) L_(b1) L_(b1) 437 L_(a427) L_(b1) L_(b1) 438 L_(a428) L_(b1) L_(b1) 439 L_(a429) L_(b1) L_(b1) 440 L_(a430) L_(b1) L_(b1) 441 L_(a431) L_(b1) L_(b1) 442 L_(a432) L_(b1) L_(b1) 443 L_(a433) L_(b1) L_(b1) 444 L_(a434) L_(b1) L_(b1) 445 L_(a435) L_(b1) L_(b1) 446 L_(a436) L_(b1) L_(b1) 447 L_(a437) L_(b1) L_(b1) 448 L_(a438) L_(b1) L_(b1) 449 L_(a439) L_(b1) L_(b1) 450 L_(a440) L_(b1) L_(b1) 451 L_(a441) L_(b1) L_(b1) 452 L_(a442) L_(b1) L_(b1) 453 L_(a443) L_(b1) L_(b1) 454 L_(a444) L_(b1) L_(b1) 455 L_(a445) L_(b1) L_(b1) 456 L_(a446) L_(b1) L_(b1) 457 L_(a447) L_(b1) L_(b1) 458 L_(a448) L_(b1) L_(b1) 459 L_(a449) L_(b1) L_(b1) 460 L_(a450) L_(b1) L_(b1) 461 L_(a451) L_(b1) L_(b1) 462 L_(a452) L_(b1) L_(b1) 463 L_(a453) L_(b1) L_(b1) 464 L_(a454) L_(b1) L_(b1) 465 L_(a455) L_(b1) L_(b1) 466 L_(a456) L_(b1) L_(b1) 467 L_(a457) L_(b1) L_(b1) 468 L_(a458) L_(b1) L_(b1) 469 L_(a459) L_(b1) L_(b1) 470 L_(a460) L_(b1) L_(b1) 471 L_(a496) L_(b1) L_(b1) 472 L_(a500) L_(b1) L_(b1) 473 L_(a502) L_(b1) L_(b1) 474 L_(a504) L_(b1) L_(b1) 475 L_(a508) L_(b1) L_(b1) 476 L_(a509) L_(b1) L_(b1) 477 L_(a510) L_(b1) L_(b1) 478 L_(a515) L_(b1) L_(b1) 479 L_(a522) L_(b1) L_(b1) 480 L_(a523) L_(b1) L_(b1) 481 L_(a524) L_(b1) L_(b1) 482 L_(a525) L_(b1) L_(b1) 483 L_(a534) L_(b1) L_(b1) 484 L_(a535) L_(b1) L_(b1) 485 L_(a567) L_(b1) L_(b1) 486 L_(a570) L_(b1) L_(b1) 487 L_(a583) L_(b1) L_(b1) 488 L_(a585) L_(b1) L_(b1) 489 L_(a586) L_(b1) L_(b1) 490 L_(a689) L_(b1) L_(b1) 491 L_(a698) L_(b1) L_(b1) 492 L_(a700) L_(b1) L_(b1) 493 L_(a1) L_(b3) L_(b3) 494 L_(a2) L_(b3) L_(b3) 495 L_(a3) L_(b3) L_(b3) 496 L_(a4) L_(b3) L_(b3) 497 L_(a5) L_(b3) L_(b3) 498 L_(a6) L_(b3) L_(b3) 499 L_(a7) L_(b3) L_(b3) 500 L_(a8) L_(b3) L_(b3) 501 L_(a9) L_(b3) L_(b3) 502 L_(a10) L_(b3) L_(b3) 503 L_(a11) L_(b3) L_(b3) 504 L_(a12) L_(b3) L_(b3) 505 L_(a13) L_(b3) L_(b3) 506 L_(a14) L_(b3) L_(b3) 507 L_(a15) L_(b3) L_(b3) 508 L_(a16) L_(b3) L_(b3) 509 L_(a17) L_(b3) L_(b3) 510 L_(a18) L_(b3) L_(b3) 511 L_(a19) L_(b3) L_(b3) 512 L_(a20) L_(b3) L_(b3) 513 L_(a21) L_(b3) L_(b3) 514 L_(a22) L_(b3) L_(b3) 515 L_(a23) L_(b3) L_(b3) 516 L_(a24) L_(b3) L_(b3) 517 L_(a25) L_(b3) L_(b3) 518 L_(a26) L_(b3) L_(b3) 519 L_(a27) L_(b3) L_(b3) 520 L_(a28) L_(b3) L_(b3) 521 L_(a29) L_(b3) L_(b3) 522 L_(a30) L_(b3) L_(b3) 523 L_(a31) L_(b3) L_(b3) 524 L_(a32) L_(b3) L_(b3) 525 L_(a33) L_(b3) L_(b3) 526 L_(a34) L_(b3) L_(b3) 527 L_(a35) L_(b3) L_(b3) 528 L_(a36) L_(b3) L_(b3) 529 L_(a37) L_(b3) L_(b3) 530 L_(a38) L_(b3) L_(b3) 531 L_(a39) L_(b3) L_(b3) 532 L_(a40) L_(b3) L_(b3) 533 L_(a41) L_(b3) L_(b3) 534 L_(a42) L_(b3) L_(b3) 535 L_(a43) L_(b3) L_(b3) 536 L_(a44) L_(b3) L_(b3) 537 L_(a45) L_(b3) L_(b3) 538 L_(a46) L_(b3) L_(b3) 539 L_(a47) L_(b3) L_(b3) 540 L_(a48) L_(b3) L_(b3) 541 L_(a49) L_(b3) L_(b3) 542 L_(a50) L_(b3) L_(b3) 543 L_(a51) L_(b3) L_(b3) 544 L_(a52) L_(b3) L_(b3) 545 L_(a53) L_(b3) L_(b3) 546 L_(a54) L_(b3) L_(b3) 547 L_(a55) L_(b3) L_(b3) 548 L_(a56) L_(b3) L_(b3) 549 L_(a57) L_(b3) L_(b3) 550 L_(a58) L_(b3) L_(b3) 551 L_(a59) L_(b3) L_(b3) 552 L_(a60) L_(b3) L_(b3) 553 L_(a61) L_(b3) L_(b3) 554 L_(a62) L_(b3) L_(b3) 555 L_(a63) L_(b3) L_(b3) 556 L_(a64) L_(b3) L_(b3) 557 L_(a65) L_(b3) L_(b3) 558 L_(a66) L_(b3) L_(b3) 559 L_(a67) L_(b3) L_(b3) 560 L_(a68) L_(b3) L_(b3) 561 L_(a69) L_(b3) L_(b3) 562 L_(a70) L_(b3) L_(b3) 563 L_(a71) L_(b3) L_(b3) 564 L_(a72) L_(b3) L_(b3) 565 L_(a73) L_(b3) L_(b3) 566 L_(a74) L_(b3) L_(b3) 567 L_(a75) L_(b3) L_(b3) 568 L_(a76) L_(b3) L_(b3) 569 L_(a77) L_(b3) L_(b3) 570 L_(a78) L_(b3) L_(b3) 571 L_(a79) L_(b3) L_(b3) 572 L_(a80) L_(b3) L_(b3) 573 L_(a81) L_(b3) L_(b3) 574 L_(a82) L_(b3) L_(b3) 575 L_(a83) L_(b3) L_(b3) 576 L_(a84) L_(b3) L_(b3) 577 L_(a85) L_(b3) L_(b3) 578 L_(a86) L_(b3) L_(b3) 579 L_(a87) L_(b3) L_(b3) 580 L_(a88) L_(b3) L_(b3) 581 L_(a89) L_(b3) L_(b3) 582 L_(a90) L_(b3) L_(b3) 583 L_(a91) L_(b3) L_(b3) 584 L_(a92) L_(b3) L_(b3) 585 L_(a93) L_(b3) L_(b3) 586 L_(a94) L_(b3) L_(b3) 587 L_(a95) L_(b3) L_(b3) 588 L_(a96) L_(b3) L_(b3) 589 L_(a97) L_(b3) L_(b3) 590 L_(a98) L_(b3) L_(b3) 591 L_(a99) L_(b3) L_(b3) 592 L_(a100) L_(b3) L_(b3) 593 L_(a101) L_(b3) L_(b3) 594 L_(a102) L_(b3) L_(b3) 595 L_(a103) L_(b3) L_(b3) 596 L_(a104) L_(b3) L_(b3) 597 L_(a105) L_(b3) L_(b3) 598 L_(a106) L_(b3) L_(b3) 599 L_(a107) L_(b3) L_(b3) 600 L_(a108) L_(b3) L_(b3) 601 L_(a109) L_(b3) L_(b3) 602 L_(a110) L_(b3) L_(b3) 603 L_(a111) L_(b3) L_(b3) 604 L_(a112) L_(b3) L_(b3) 605 L_(a113) L_(b3) L_(b3) 606 L_(a114) L_(b3) L_(b3) 607 L_(a115) L_(b3) L_(b3) 608 L_(a116) L_(b3) L_(b3) 609 L_(a117) L_(b3) L_(b3) 610 L_(a118) L_(b3) L_(b3) 611 L_(a119) L_(b3) L_(b3) 612 L_(a120) L_(b3) L_(b3) 613 L_(a121) L_(b3) L_(b3) 614 L_(a122) L_(b3) L_(b3) 615 L_(a123) L_(b3) L_(b3) 616 L_(a124) L_(b3) L_(b3) 617 L_(a125) L_(b3) L_(b3) 618 L_(a126) L_(b3) L_(b3) 619 L_(a127) L_(b3) L_(b3) 620 L_(a128) L_(b3) L_(b3) 621 L_(a129) L_(b3) L_(b3) 622 L_(a130) L_(b3) L_(b3) 623 L_(a131) L_(b3) L_(b3) 624 L_(a132) L_(b3) L_(b3) 625 L_(a133) L_(b3) L_(b3) 626 L_(a134) L_(b3) L_(b3) 627 L_(a135) L_(b3) L_(b3) 628 L_(a136) L_(b3) L_(b3) 629 L_(a137) L_(b3) L_(b3) 630 L_(a138) L_(b3) L_(b3) 631 L_(a139) L_(b3) L_(b3) 632 L_(a140) L_(b3) L_(b3) 633 L_(a141) L_(b3) L_(b3) 634 L_(a142) L_(b3) L_(b3) 635 L_(a143) L_(b3) L_(b3) 636 L_(a144) L_(b3) L_(b3) 637 L_(a145) L_(b3) L_(b3) 638 L_(a146) L_(b3) L_(b3) 639 L_(a147) L_(b3) L_(b3) 640 L_(a148) L_(b3) L_(b3) 641 L_(a149) L_(b3) L_(b3) 642 L_(a150) L_(b3) L_(b3) 643 L_(a151) L_(b3) L_(b3) 644 L_(a152) L_(b3) L_(b3) 645 L_(a153) L_(b3) L_(b3) 646 L_(a154) L_(b3) L_(b3) 647 L_(a155) L_(b3) L_(b3) 648 L_(a156) L_(b3) L_(b3) 649 L_(a157) L_(b3) L_(b3) 650 L_(a158) L_(b3) L_(b3) 651 L_(a159) L_(b3) L_(b3) 652 L_(a160) L_(b3) L_(b3) 653 L_(a161) L_(b3) L_(b3) 654 L_(a162) L_(b3) L_(b3) 655 L_(a163) L_(b3) L_(b3) 656 L_(a164) L_(b3) L_(b3) 657 L_(a165) L_(b3) L_(b3) 658 L_(a166) L_(b3) L_(b3) 659 L_(a167) L_(b3) L_(b3) 660 L_(a168) L_(b3) L_(b3) 661 L_(a169) L_(b3) L_(b3) 662 L_(a170) L_(b3) L_(b3) 663 L_(a171) L_(b3) L_(b3) 664 L_(a172) L_(b3) L_(b3) 665 L_(a173) L_(b3) L_(b3) 666 L_(a174) L_(b3) L_(b3) 667 L_(a175) L_(b3) L_(b3) 668 L_(a176) L_(b3) L_(b3) 669 L_(a177) L_(b3) L_(b3) 670 L_(a178) L_(b3) L_(b3) 671 L_(a179) L_(b3) L_(b3) 672 L_(a180) L_(b3) L_(b3) 673 L_(a181) L_(b3) L_(b3) 674 L_(a182) L_(b3) L_(b3) 675 L_(a183) L_(b3) L_(b3) 676 L_(a184) L_(b3) L_(b3) 677 L_(a185) L_(b3) L_(b3) 678 L_(a186) L_(b3) L_(b3) 679 L_(a187) L_(b3) L_(b3) 680 L_(a188) L_(b3) L_(b3) 681 L_(a189) L_(b3) L_(b3) 682 L_(a190) L_(b3) L_(b3) 683 L_(a191) L_(b3) L_(b3) 684 L_(a192) L_(b3) L_(b3) 685 L_(a193) L_(b3) L_(b3) 686 L_(a194) L_(b3) L_(b3) 687 L_(a195) L_(b3) L_(b3) 688 L_(a196) L_(b3) L_(b3) 689 L_(a197) L_(b3) L_(b3) 690 L_(a198) L_(b3) L_(b3) 691 L_(a199) L_(b3) L_(b3) 692 L_(a200) L_(b3) L_(b3) 693 L_(a201) L_(b3) L_(b3) 694 L_(a202) L_(b3) L_(b3) 695 L_(a203) L_(b3) L_(b3) 696 L_(a204) L_(b3) L_(b3) 697 L_(a205) L_(b3) L_(b3) 698 L_(a206) L_(b3) L_(b3) 699 L_(a207) L_(b3) L_(b3) 700 L_(a208) L_(b3) L_(b3) 701 L_(a209) L_(b3) L_(b3) 702 L_(a210) L_(b3) L_(b3) 703 L_(a211) L_(b3) L_(b3) 704 L_(a212) L_(b3) L_(b3) 705 L_(a213) L_(b3) L_(b3) 706 L_(a214) L_(b3) L_(b3) 707 L_(a215) L_(b3) L_(b3) 708 L_(a216) L_(b3) L_(b3) 709 L_(a217) L_(b3) L_(b3) 710 L_(a218) L_(b3) L_(b3) 711 L_(a219) L_(b3) L_(b3) 712 L_(a220) L_(b3) L_(b3) 713 L_(a221) L_(b3) L_(b3) 714 L_(a222) L_(b3) L_(b3) 715 L_(a223) L_(b3) L_(b3) 716 L_(a224) L_(b3) L_(b3) 717 L_(a225) L_(b3) L_(b3) 718 L_(a226) L_(b3) L_(b3) 719 L_(a227) L_(b3) L_(b3) 720 L_(a228) L_(b3) L_(b3) 721 L_(a229) L_(b3) L_(b3) 722 L_(a230) L_(b3) L_(b3) 723 L_(a231) L_(b3) L_(b3) 724 L_(a232) L_(b3) L_(b3) 725 L_(a233) L_(b3) L_(b3) 726 L_(a234) L_(b3) L_(b3) 727 L_(a235) L_(b3) L_(b3) 728 L_(a236) L_(b3) L_(b3) 729 L_(a237) L_(b3) L_(b3) 730 L_(a238) L_(b3) L_(b3) 731 L_(a239) L_(b3) L_(b3) 732 L_(a240) L_(b3) L_(b3) 733 L_(a241) L_(b3) L_(b3) 734 L_(a242) L_(b3) L_(b3) 735 L_(a243) L_(b3) L_(b3) 736 L_(a244) L_(b3) L_(b3) 737 L_(a245) L_(b3) L_(b3) 738 L_(a246) L_(b3) L_(b3) 739 L_(a247) L_(b3) L_(b3) 740 L_(a248) L_(b3) L_(b3) 741 L_(a249) L_(b3) L_(b3) 742 L_(a250) L_(b3) L_(b3) 743 L_(a251) L_(b3) L_(b3) 744 L_(a252) L_(b3) L_(b3) 745 L_(a253) L_(b3) L_(b3) 746 L_(a254) L_(b3) L_(b3) 747 L_(a255) L_(b3) L_(b3) 748 L_(a256) L_(b3) L_(b3) 749 L_(a257) L_(b3) L_(b3) 750 L_(a258) L_(b3) L_(b3) 751 L_(a259) L_(b3) L_(b3) 752 L_(a260) L_(b3) L_(b3) 753 L_(a261) L_(b3) L_(b3) 754 L_(a262) L_(b3) L_(b3) 755 L_(a263) L_(b3) L_(b3) 756 L_(a264) L_(b3) L_(b3) 757 L_(a265) L_(b3) L_(b3) 758 L_(a266) L_(b3) L_(b3) 759 L_(a267) L_(b3) L_(b3) 760 L_(a268) L_(b3) L_(b3) 761 L_(a269) L_(b3) L_(b3) 762 L_(a270) L_(b3) L_(b3) 763 L_(a271) L_(b3) L_(b3) 764 L_(a272) L_(b3) L_(b3) 765 L_(a273) L_(b3) L_(b3) 766 L_(a274) L_(b3) L_(b3) 767 L_(a275) L_(b3) L_(b3) 768 L_(a276) L_(b3) L_(b3) 769 L_(a277) L_(b3) L_(b3) 770 L_(a278) L_(b3) L_(b3) 771 L_(a279) L_(b3) L_(b3) 772 L_(a280) L_(b3) L_(b3) 773 L_(a281) L_(b3) L_(b3) 774 L_(a282) L_(b3) L_(b3) 775 L_(a283) L_(b3) L_(b3) 776 L_(a284) L_(b3) L_(b3) 777 L_(a285) L_(b3) L_(b3) 778 L_(a286) L_(b3) L_(b3) 779 L_(a287) L_(b3) L_(b3) 780 L_(a288) L_(b3) L_(b3) 781 L_(a289) L_(b3) L_(b3) 782 L_(a290) L_(b3) L_(b3) 783 L_(a291) L_(b3) L_(b3) 784 L_(a292) L_(b3) L_(b3) 785 L_(a293) L_(b3) L_(b3) 786 L_(a294) L_(b3) L_(b3) 787 L_(a295) L_(b3) L_(b3) 788 L_(a296) L_(b3) L_(b3) 789 L_(a297) L_(b3) L_(b3) 790 L_(a298) L_(b3) L_(b3) 791 L_(a299) L_(b3) L_(b3) 792 L_(a300) L_(b3) L_(b3) 793 L_(a301) L_(b3) L_(b3) 794 L_(a302) L_(b3) L_(b3) 795 L_(a303) L_(b3) L_(b3) 796 L_(a304) L_(b3) L_(b3) 797 L_(a305) L_(b3) L_(b3) 798 L_(a306) L_(b3) L_(b3) 799 L_(a307) L_(b3) L_(b3) 800 L_(a308) L_(b3) L_(b3) 801 L_(a309) L_(b3) L_(b3) 802 L_(a310) L_(b3) L_(b3) 803 L_(a311) L_(b3) L_(b3) 804 L_(a312) L_(b3) L_(b3) 805 L_(a313) L_(b3) L_(b3) 806 L_(a314) L_(b3) L_(b3) 807 L_(a315) L_(b3) L_(b3) 808 L_(a316) L_(b3) L_(b3) 809 L_(a317) L_(b3) L_(b3) 810 L_(a318) L_(b3) L_(b3) 811 L_(a319) L_(b3) L_(b3) 812 L_(a320) L_(b3) L_(b3) 813 L_(a321) L_(b3) L_(b3) 814 L_(a322) L_(b3) L_(b3) 815 L_(a323) L_(b3) L_(b3) 816 L_(a324) L_(b3) L_(b3) 817 L_(a325) L_(b3) L_(b3) 818 L_(a326) L_(b3) L_(b3) 819 L_(a327) L_(b3) L_(b3) 820 L_(a328) L_(b3) L_(b3) 821 L_(a329) L_(b3) L_(b3) 822 L_(a330) L_(b3) L_(b3) 823 L_(a331) L_(b3) L_(b3) 824 L_(a332) L_(b3) L_(b3) 825 L_(a333) L_(b3) L_(b3) 826 L_(a334) L_(b3) L_(b3) 827 L_(a335) L_(b3) L_(b3) 828 L_(a336) L_(b3) L_(b3) 829 L_(a337) L_(b3) L_(b3) 830 L_(a338) L_(b3) L_(b3) 831 L_(a339) L_(b3) L_(b3) 832 L_(a340) L_(b3) L_(b3) 833 L_(a341) L_(b3) L_(b3) 834 L_(a342) L_(b3) L_(b3) 835 L_(a343) L_(b3) L_(b3) 836 L_(a344) L_(b3) L_(b3) 837 L_(a345) L_(b3) L_(b3) 838 L_(a346) L_(b3) L_(b3) 839 L_(a347) L_(b3) L_(b3) 840 L_(a348) L_(b3) L_(b3) 841 L_(a349) L_(b3) L_(b3) 842 L_(a350) L_(b3) L_(b3) 843 L_(a351) L_(b3) L_(b3) 844 L_(a352) L_(b3) L_(b3) 845 L_(a353) L_(b3) L_(b3) 846 L_(a354) L_(b3) L_(b3) 847 L_(a355) L_(b3) L_(b3) 848 L_(a356) L_(b3) L_(b3) 849 L_(a357) L_(b3) L_(b3) 850 L_(a358) L_(b3) L_(b3) 851 L_(a359) L_(b3) L_(b3) 852 L_(a360) L_(b3) L_(b3) 853 L_(a361) L_(b3) L_(b3) 854 L_(a362) L_(b3) L_(b3) 855 L_(a363) L_(b3) L_(b3) 856 L_(a364) L_(b3) L_(b3) 857 L_(a365) L_(b3) L_(b3) 858 L_(a366) L_(b3) L_(b3) 859 L_(a367) L_(b3) L_(b3) 860 L_(a368) L_(b3) L_(b3) 861 L_(a369) L_(b3) L_(b3) 862 L_(a370) L_(b3) L_(b3) 863 L_(a371) L_(b3) L_(b3) 864 L_(a372) L_(b3) L_(b3) 865 L_(a373) L_(b3) L_(b3) 866 L_(a374) L_(b3) L_(b3) 867 L_(a375) L_(b3) L_(b3) 868 L_(a376) L_(b3) L_(b3) 869 L_(a377) L_(b3) L_(b3) 870 L_(a378) L_(b3) L_(b3) 871 L_(a379) L_(b3) L_(b3) 872 L_(a380) L_(b3) L_(b3) 873 L_(a381) L_(b3) L_(b3) 874 L_(a382) L_(b3) L_(b3) 875 L_(a383) L_(b3) L_(b3) 876 L_(a384) L_(b3) L_(b3) 877 L_(a385) L_(b3) L_(b3) 878 L_(a386) L_(b3) L_(b3) 879 L_(a387) L_(b3) L_(b3) 880 L_(a388) L_(b3) L_(b3) 881 L_(a389) L_(b3) L_(b3) 882 L_(a390) L_(b3) L_(b3) 883 L_(a391) L_(b3) L_(b3) 884 L_(a392) L_(b3) L_(b3) 885 L_(a393) L_(b3) L_(b3) 886 L_(a394) L_(b3) L_(b3) 887 L_(a395) L_(b3) L_(b3) 888 L_(a396) L_(b3) L_(b3) 889 L_(a397) L_(b3) L_(b3) 890 L_(a398) L_(b3) L_(b3) 891 L_(a399) L_(b3) L_(b3) 892 L_(a400) L_(b3) L_(b3) 893 L_(a401) L_(b3) L_(b3) 894 L_(a402) L_(b3) L_(b3) 895 L_(a403) L_(b3) L_(b3) 896 L_(a404) L_(b3) L_(b3) 897 L_(a405) L_(b3) L_(b3) 898 L_(a406) L_(b3) L_(b3) 899 L_(a407) L_(b3) L_(b3) 900 L_(a408) L_(b3) L_(b3) 901 L_(a409) L_(b3) L_(b3) 902 L_(a410) L_(b3) L_(b3) 903 L_(a411) L_(b3) L_(b3) 904 L_(a412) L_(b3) L_(b3) 905 L_(a413) L_(b3) L_(b3) 906 L_(a414) L_(b3) L_(b3) 907 L_(a415) L_(b3) L_(b3) 908 L_(a416) L_(b3) L_(b3) 909 L_(a417) L_(b3) L_(b3) 910 L_(a418) L_(b3) L_(b3) 911 L_(a419) L_(b3) L_(b3) 912 L_(a420) L_(b3) L_(b3) 913 L_(a421) L_(b3) L_(b3) 914 L_(a422) L_(b3) L_(b3) 915 L_(a423) L_(b3) L_(b3) 916 L_(a424) L_(b3) L_(b3) 917 L_(a425) L_(b3) L_(b3) 918 L_(a426) L_(b3) L_(b3) 919 L_(a427) L_(b3) L_(b3) 920 L_(a428) L_(b3) L_(b3) 921 L_(a429) L_(b3) L_(b3) 922 L_(a430) L_(b3) L_(b3) 923 L_(a431) L_(b3) L_(b3) 924 L_(a432) L_(b3) L_(b3) 925 L_(a433) L_(b3) L_(b3) 926 L_(a434) L_(b3) L_(b3) 927 L_(a435) L_(b3) L_(b3) 928 L_(a436) L_(b3) L_(b3) 929 L_(a437) L_(b3) L_(b3) 930 L_(a438) L_(b3) L_(b3) 931 L_(a439) L_(b3) L_(b3) 932 L_(a440) L_(b3) L_(b3) 933 L_(a441) L_(b3) L_(b3) 934 L_(a442) L_(b3) L_(b3) 935 L_(a443) L_(b3) L_(b3) 936 L_(a444) L_(b3) L_(b3) 937 L_(a445) L_(b3) L_(b3) 938 L_(a446) L_(b3) L_(b3) 939 L_(a447) L_(b3) L_(b3) 940 L_(a448) L_(b3) L_(b3) 941 L_(a449) L_(b3) L_(b3) 942 L_(a450) L_(b3) L_(b3) 943 L_(a451) L_(b3) L_(b3) 944 L_(a452) L_(b3) L_(b3) 945 L_(a453) L_(b3) L_(b3) 946 L_(a454) L_(b3) L_(b3) 947 L_(a455) L_(b3) L_(b3) 948 L_(a456) L_(b3) L_(b3) 949 L_(a457) L_(b3) L_(b3) 950 L_(a458) L_(b3) L_(b3) 951 L_(a459) L_(b3) L_(b3) 952 L_(a460) L_(b3) L_(b3) 953 L_(a496) L_(b3) L_(b3) 954 L_(a500) L_(b3) L_(b3) 955 L_(a502) L_(b3) L_(b3) 956 L_(a504) L_(b3) L_(b3) 957 L_(a508) L_(b3) L_(b3) 958 L_(a509) L_(b3) L_(b3) 959 L_(a510) L_(b3) L_(b3) 960 L_(a515) L_(b3) L_(b3) 961 L_(a522) L_(b3) L_(b3) 962 L_(a523) L_(b3) L_(b3) 963 L_(a524) L_(b3) L_(b3) 964 L_(a525) L_(b3) L_(b3) 965 L_(a534) L_(b3) L_(b3) 966 L_(a535) L_(b3) L_(b3) 967 L_(a567) L_(b3) L_(b3) 968 L_(a570) L_(b3) L_(b3) 969 L_(a583) L_(b3) L_(b3) 970 L_(a585) L_(b3) L_(b3) 971 L_(a586) L_(b3) L_(b3) 972 L_(a689) L_(b3) L_(b3) 973 L_(a698) L_(b3) L_(b3) 974 L_(a700) L_(b3) L_(b3) 975 L_(a1) L_(b81) L_(b81) 976 L_(a2) L_(b81) L_(b81) 977 L_(a3) L_(b81) L_(b81) 978 L_(a4) L_(b81) L_(b81) 979 L_(a5) L_(b81) L_(b81) 980 L_(a6) L_(b81) L_(b81) 981 L_(a7) L_(b81) L_(b81) 982 L_(a8) L_(b81) L_(b81) 983 L_(a9) L_(b81) L_(b81) 984 L_(a10) L_(b81) L_(b81) 985 L_(a11) L_(b81) L_(b81) 986 L_(a12) L_(b81) L_(b81) 987 L_(a13) L_(b81) L_(b81) 988 L_(a14) L_(b81) L_(b81) 989 L_(a15) L_(b81) L_(b81) 990 L_(a16) L_(b81) L_(b81) 991 L_(a17) L_(b81) L_(b81) 992 L_(a18) L_(b81) L_(b81) 993 L_(a19) L_(b81) L_(b81) 994 L_(a20) L_(b81) L_(b81) 995 L_(a21) L_(b81) L_(b81) 996 L_(a22) L_(b81) L_(b81) 997 L_(a23) L_(b81) L_(b81) 998 L_(a24) L_(b81) L_(b81) 999 L_(a25) L_(b81) L_(b81) 1000 L_(a26) L_(b81) L_(b81) 1001 L_(a27) L_(b81) L_(b81) 1002 L_(a28) L_(b81) L_(b81) 1003 L_(a29) L_(b81) L_(b81) 1004 L_(a30) L_(b81) L_(b81) 1005 L_(a31) L_(b81) L_(b81) 1006 L_(a32) L_(b81) L_(b81) 1007 L_(a33) L_(b81) L_(b81) 1008 L_(a34) L_(b81) L_(b81) 1009 L_(a35) L_(b81) L_(b81) 1010 L_(a36) L_(b81) L_(b81) 1011 L_(a37) L_(b81) L_(b81) 1012 L_(a38) L_(b81) L_(b81) 1013 L_(a39) L_(b81) L_(b81) 1014 L_(a40) L_(b81) L_(b81) 1015 L_(a41) L_(b81) L_(b81) 1016 L_(a42) L_(b81) L_(b81) 1017 L_(a43) L_(b81) L_(b81) 1018 L_(a44) L_(b81) L_(b81) 1019 L_(a45) L_(b81) L_(b81) 1020 L_(a46) L_(b81) L_(b81) 1021 L_(a47) L_(b81) L_(b81) 1022 L_(a48) L_(b81) L_(b81) 1023 L_(a49) L_(b81) L_(b81) 1024 L_(a50) L_(b81) L_(b81) 1025 L_(a51) L_(b81) L_(b81) 1026 L_(a52) L_(b81) L_(b81) 1027 L_(a53) L_(b81) L_(b81) 1028 L_(a54) L_(b81) L_(b81) 1029 L_(a55) L_(b81) L_(b81) 1030 L_(a56) L_(b81) L_(b81) 1031 L_(a57) L_(b81) L_(b81) 1032 L_(a58) L_(b81) L_(b81) 1033 L_(a59) L_(b81) L_(b81) 1034 L_(a60) L_(b81) L_(b81) 1035 L_(a61) L_(b81) L_(b81) 1036 L_(a62) L_(b81) L_(b81) 1037 L_(a63) L_(b81) L_(b81) 1038 L_(a64) L_(b81) L_(b81) 1039 L_(a65) L_(b81) L_(b81) 1040 L_(a66) L_(b81) L_(b81) 1041 L_(a67) L_(b81) L_(b81) 1042 L_(a68) L_(b81) L_(b81) 1043 L_(a69) L_(b81) L_(b81) 1044 L_(a70) L_(b81) L_(b81) 1045 L_(a71) L_(b81) L_(b81) 1046 L_(a72) L_(b81) L_(b81) 1047 L_(a73) L_(b81) L_(b81) 1048 L_(a74) L_(b81) L_(b81) 1049 L_(a75) L_(b81) L_(b81) 1050 L_(a76) L_(b81) L_(b81) 1051 L_(a77) L_(b81) L_(b81) 1052 L_(a78) L_(b81) L_(b81) 1053 L_(a79) L_(b81) L_(b81) 1054 L_(a80) L_(b81) L_(b81) 1055 L_(a81) L_(b81) L_(b81) 1056 L_(a82) L_(b81) L_(b81) 1057 L_(a83) L_(b81) L_(b81) 1058 L_(a84) L_(b81) L_(b81) 1059 L_(a85) L_(b81) L_(b81) 1060 L_(a86) L_(b81) L_(b81) 1061 L_(a87) L_(b81) L_(b81) 1062 L_(a88) L_(b81) L_(b81) 1063 L_(a89) L_(b81) L_(b81) 1064 L_(a90) L_(b81) L_(b81) 1065 L_(a91) L_(b81) L_(b81) 1066 L_(a92) L_(b81) L_(b81) 1067 L_(a93) L_(b81) L_(b81) 1068 L_(a94) L_(b81) L_(b81) 1069 L_(a95) L_(b81) L_(b81) 1070 L_(a96) L_(b81) L_(b81) 1071 L_(a97) L_(b81) L_(b81) 1072 L_(a98) L_(b81) L_(b81) 1073 L_(a99) L_(b81) L_(b81) 1074 L_(a100) L_(b81) L_(b81) 1075 L_(a101) L_(b81) L_(b81) 1076 L_(a102) L_(b81) L_(b81) 1077 L_(a103) L_(b81) L_(b81) 1078 L_(a104) L_(b81) L_(b81) 1079 L_(a105) L_(b81) L_(b81) 1080 L_(a106) L_(b81) L_(b81) 1081 L_(a107) L_(b81) L_(b81) 1082 L_(a108) L_(b81) L_(b81) 1083 L_(a109) L_(b81) L_(b81) 1084 L_(a110) L_(b81) L_(b81) 1085 L_(a111) L_(b81) L_(b81) 1086 L_(a112) L_(b81) L_(b81) 1087 L_(a113) L_(b81) L_(b81) 1088 L_(a114) L_(b81) L_(b81) 1089 L_(a115) L_(b81) L_(b81) 1090 L_(a116) L_(b81) L_(b81) 1091 L_(a117) L_(b81) L_(b81) 1092 L_(a118) L_(b81) L_(b81) 1093 L_(a119) L_(b81) L_(b81) 1094 L_(a120) L_(b81) L_(b81) 1095 L_(a121) L_(b81) L_(b81) 1096 L_(a122) L_(b81) L_(b81) 1097 L_(a123) L_(b81) L_(b81) 1098 L_(a124) L_(b81) L_(b81) 1099 L_(a125) L_(b81) L_(b81) 1100 L_(a126) L_(b81) L_(b81) 1101 L_(a127) L_(b81) L_(b81) 1102 L_(a128) L_(b81) L_(b81) 1103 L_(a129) L_(b81) L_(b81) 1104 L_(a130) L_(b81) L_(b81) 1105 L_(a131) L_(b81) L_(b81) 1106 L_(a132) L_(b81) L_(b81) 1107 L_(a133) L_(b81) L_(b81) 1108 L_(a134) L_(b81) L_(b81) 1109 L_(a135) L_(b81) L_(b81) 1110 L_(a136) L_(b81) L_(b81) 1111 L_(a137) L_(b81) L_(b81) 1112 L_(a138) L_(b81) L_(b81) 1113 L_(a139) L_(b81) L_(b81) 1114 L_(a140) L_(b81) L_(b81) 1115 L_(a141) L_(b81) L_(b81) 1116 L_(a142) L_(b81) L_(b81) 1117 L_(a143) L_(b81) L_(b81) 1118 L_(a144) L_(b81) L_(b81) 1119 L_(a145) L_(b81) L_(b81) 1120 L_(a146) L_(b81) L_(b81) 1121 L_(a147) L_(b81) L_(b81) 1122 L_(a148) L_(b81) L_(b81) 1123 L_(a149) L_(b81) L_(b81) 1124 L_(a150) L_(b81) L_(b81) 1125 L_(a151) L_(b81) L_(b81) 1126 L_(a152) L_(b81) L_(b81) 1127 L_(a153) L_(b81) L_(b81) 1128 L_(a154) L_(b81) L_(b81) 1129 L_(a155) L_(b81) L_(b81) 1130 L_(a156) L_(b81) L_(b81) 1131 L_(a157) L_(b81) L_(b81) 1132 L_(a158) L_(b81) L_(b81) 1133 L_(a159) L_(b81) L_(b81) 1134 L_(a160) L_(b81) L_(b81) 1135 L_(a161) L_(b81) L_(b81) 1136 L_(a162) L_(b81) L_(b81) 1137 L_(a163) L_(b81) L_(b81) 1138 L_(a164) L_(b81) L_(b81) 1139 L_(a165) L_(b81) L_(b81) 1140 L_(a166) L_(b81) L_(b81) 1141 L_(a167) L_(b81) L_(b81) 1142 L_(a168) L_(b81) L_(b81) 1143 L_(a169) L_(b81) L_(b81) 1144 L_(a170) L_(b81) L_(b81) 1145 L_(a171) L_(b81) L_(b81) 1146 L_(a172) L_(b81) L_(b81) 1147 L_(a173) L_(b81) L_(b81) 1148 L_(a174) L_(b81) L_(b81) 1149 L_(a175) L_(b81) L_(b81) 1150 L_(a176) L_(b81) L_(b81) 1151 L_(a177) L_(b81) L_(b81) 1152 L_(a178) L_(b81) L_(b81) 1153 L_(a179) L_(b81) L_(b81) 1154 L_(a180) L_(b81) L_(b81) 1155 L_(a181) L_(b81) L_(b81) 1156 L_(a182) L_(b81) L_(b81) 1157 L_(a183) L_(b81) L_(b81) 1158 L_(a184) L_(b81) L_(b81) 1159 L_(a185) L_(b81) L_(b81) 1160 L_(a186) L_(b81) L_(b81) 1161 L_(a187) L_(b81) L_(b81) 1162 L_(a188) L_(b81) L_(b81) 1163 L_(a189) L_(b81) L_(b81) 1164 L_(a190) L_(b81) L_(b81) 1165 L_(a191) L_(b81) L_(b81) 1166 L_(a192) L_(b81) L_(b81) 1167 L_(a193) L_(b81) L_(b81) 1168 L_(a194) L_(b81) L_(b81) 1169 L_(a195) L_(b81) L_(b81) 1170 L_(a196) L_(b81) L_(b81) 1171 L_(a197) L_(b81) L_(b81) 1172 L_(a198) L_(b81) L_(b81) 1173 L_(a199) L_(b81) L_(b81) 1174 L_(a200) L_(b81) L_(b81) 1175 L_(a201) L_(b81) L_(b81) 1176 L_(a202) L_(b81) L_(b81) 1177 L_(a203) L_(b81) L_(b81) 1178 L_(a204) L_(b81) L_(b81) 1179 L_(a205) L_(b81) L_(b81) 1180 L_(a206) L_(b81) L_(b81) 1181 L_(a207) L_(b81) L_(b81) 1182 L_(a208) L_(b81) L_(b81) 1183 L_(a209) L_(b81) L_(b81) 1184 L_(a210) L_(b81) L_(b81) 1185 L_(a211) L_(b81) L_(b81) 1186 L_(a212) L_(b81) L_(b81) 1187 L_(a213) L_(b81) L_(b81) 1188 L_(a214) L_(b81) L_(b81) 1189 L_(a215) L_(b81) L_(b81) 1190 L_(a216) L_(b81) L_(b81) 1191 L_(a217) L_(b81) L_(b81) 1192 L_(a218) L_(b81) L_(b81) 1193 L_(a219) L_(b81) L_(b81) 1194 L_(a220) L_(b81) L_(b81) 1195 L_(a221) L_(b81) L_(b81) 1196 L_(a222) L_(b81) L_(b81) 1197 L_(a223) L_(b81) L_(b81) 1198 L_(a224) L_(b81) L_(b81) 1199 L_(a225) L_(b81) L_(b81) 1200 L_(a226) L_(b81) L_(b81) 1201 L_(a227) L_(b81) L_(b81) 1202 L_(a228) L_(b81) L_(b81) 1203 L_(a229) L_(b81) L_(b81) 1204 L_(a230) L_(b81) L_(b81) 1205 L_(a231) L_(b81) L_(b81) 1206 L_(a232) L_(b81) L_(b81) 1207 L_(a233) L_(b81) L_(b81) 1208 L_(a234) L_(b81) L_(b81) 1209 L_(a235) L_(b81) L_(b81) 1210 L_(a236) L_(b81) L_(b81) 1211 L_(a237) L_(b81) L_(b81) 1212 L_(a238) L_(b81) L_(b81) 1213 L_(a239) L_(b81) L_(b81) 1214 L_(a240) L_(b81) L_(b81) 1215 L_(a241) L_(b81) L_(b81) 1216 L_(a242) L_(b81) L_(b81) 1217 L_(a243) L_(b81) L_(b81) 1218 L_(a244) L_(b81) L_(b81) 1219 L_(a245) L_(b81) L_(b81) 1220 L_(a246) L_(b81) L_(b81) 1221 L_(a247) L_(b81) L_(b81) 1222 L_(a248) L_(b81) L_(b81) 1223 L_(a249) L_(b81) L_(b81) 1224 L_(a250) L_(b81) L_(b81) 1225 L_(a251) L_(b81) L_(b81) 1226 L_(a252) L_(b81) L_(b81) 1227 L_(a253) L_(b81) L_(b81) 1228 L_(a254) L_(b81) L_(b81) 1229 L_(a255) L_(b81) L_(b81) 1230 L_(a256) L_(b81) L_(b81) 1231 L_(a257) L_(b81) L_(b81) 1232 L_(a258) L_(b81) L_(b81) 1233 L_(a259) L_(b81) L_(b81) 1234 L_(a260) L_(b81) L_(b81) 1235 L_(a261) L_(b81) L_(b81) 1236 L_(a262) L_(b81) L_(b81) 1237 L_(a263) L_(b81) L_(b81) 1238 L_(a264) L_(b81) L_(b81) 1239 L_(a265) L_(b81) L_(b81) 1240 L_(a266) L_(b81) L_(b81) 1241 L_(a267) L_(b81) L_(b81) 1242 L_(a268) L_(b81) L_(b81) 1243 L_(a269) L_(b81) L_(b81) 1244 L_(a270) L_(b81) L_(b81) 1245 L_(a271) L_(b81) L_(b81) 1246 L_(a272) L_(b81) L_(b81) 1247 L_(a273) L_(b81) L_(b81) 1248 L_(a274) L_(b81) L_(b81) 1249 L_(a275) L_(b81) L_(b81) 1250 L_(a276) L_(b81) L_(b81) 1251 L_(a277) L_(b81) L_(b81) 1252 L_(a278) L_(b81) L_(b81) 1253 L_(a279) L_(b81) L_(b81) 1254 L_(a280) L_(b81) L_(b81) 1255 L_(a281) L_(b81) L_(b81) 1256 L_(a282) L_(b81) L_(b81) 1257 L_(a283) L_(b81) L_(b81) 1258 L_(a284) L_(b81) L_(b81) 1259 L_(a285) L_(b81) L_(b81) 1260 L_(a286) L_(b81) L_(b81) 1261 L_(a287) L_(b81) L_(b81) 1262 L_(a288) L_(b81) L_(b81) 1263 L_(a289) L_(b81) L_(b81) 1264 L_(a290) L_(b81) L_(b81) 1265 L_(a291) L_(b81) L_(b81) 1266 L_(a292) L_(b81) L_(b81) 1267 L_(a293) L_(b81) L_(b81) 1268 L_(a294) L_(b81) L_(b81) 1269 L_(a295) L_(b81) L_(b81) 1270 L_(a296) L_(b81) L_(b81) 1271 L_(a297) L_(b81) L_(b81) 1272 L_(a298) L_(b81) L_(b81) 1273 L_(a299) L_(b81) L_(b81) 1274 L_(a300) L_(b81) L_(b81) 1275 L_(a301) L_(b81) L_(b81) 1276 L_(a302) L_(b81) L_(b81) 1277 L_(a303) L_(b81) L_(b81) 1278 L_(a304) L_(b81) L_(b81) 1279 L_(a305) L_(b81) L_(b81) 1280 L_(a306) L_(b81) L_(b81) 1281 L_(a307) L_(b81) L_(b81) 1282 L_(a308) L_(b81) L_(b81) 1283 L_(a309) L_(b81) L_(b81) 1284 L_(a310) L_(b81) L_(b81) 1285 L_(a311) L_(b81) L_(b81) 1286 L_(a312) L_(b81) L_(b81) 1287 L_(a313) L_(b81) L_(b81) 1288 L_(a314) L_(b81) L_(b81) 1289 L_(a315) L_(b81) L_(b81) 1290 L_(a316) L_(b81) L_(b81) 1291 L_(a317) L_(b81) L_(b81) 1292 L_(a318) L_(b81) L_(b81) 1293 L_(a319) L_(b81) L_(b81) 1294 L_(a320) L_(b81) L_(b81) 1295 L_(a321) L_(b81) L_(b81) 1296 L_(a322) L_(b81) L_(b81) 1297 L_(a323) L_(b81) L_(b81) 1298 L_(a324) L_(b81) L_(b81) 1299 L_(a325) L_(b81) L_(b81) 1300 L_(a326) L_(b81) L_(b81) 1301 L_(a327) L_(b81) L_(b81) 1302 L_(a328) L_(b81) L_(b81) 1303 L_(a329) L_(b81) L_(b81) 1304 L_(a330) L_(b81) L_(b81) 1305 L_(a331) L_(b81) L_(b81) 1306 L_(a332) L_(b81) L_(b81) 1307 L_(a333) L_(b81) L_(b81) 1308 L_(a334) L_(b81) L_(b81) 1309 L_(a335) L_(b81) L_(b81) 1310 L_(a336) L_(b81) L_(b81) 1311 L_(a337) L_(b81) L_(b81) 1312 L_(a338) L_(b81) L_(b81) 1313 L_(a339) L_(b81) L_(b81) 1314 L_(a340) L_(b81) L_(b81) 1315 L_(a341) L_(b81) L_(b81) 1316 L_(a342) L_(b81) L_(b81) 1317 L_(a343) L_(b81) L_(b81) 1318 L_(a344) L_(b81) L_(b81) 1319 L_(a345) L_(b81) L_(b81) 1320 L_(a346) L_(b81) L_(b81) 1321 L_(a347) L_(b81) L_(b81) 1322 L_(a348) L_(b81) L_(b81) 1323 L_(a349) L_(b81) L_(b81) 1324 L_(a350) L_(b81) L_(b81) 1325 L_(a351) L_(b81) L_(b81) 1326 L_(a352) L_(b81) L_(b81) 1327 L_(a353) L_(b81) L_(b81) 1328 L_(a354) L_(b81) L_(b81) 1329 L_(a355) L_(b81) L_(b81) 1330 L_(a356) L_(b81) L_(b81) 1331 L_(a357) L_(b81) L_(b81) 1332 L_(a358) L_(b81) L_(b81) 1333 L_(a359) L_(b81) L_(b81) 1334 L_(a360) L_(b81) L_(b81) 1335 L_(a361) L_(b81) L_(b81) 1336 L_(a362) L_(b81) L_(b81) 1337 L_(a363) L_(b81) L_(b81) 1338 L_(a364) L_(b81) L_(b81) 1339 L_(a365) L_(b81) L_(b81) 1340 L_(a366) L_(b81) L_(b81) 1341 L_(a367) L_(b81) L_(b81) 1342 L_(a368) L_(b81) L_(b81) 1343 L_(a369) L_(b81) L_(b81) 1344 L_(a370) L_(b81) L_(b81) 1345 L_(a371) L_(b81) L_(b81) 1346 L_(a372) L_(b81) L_(b81) 1347 L_(a373) L_(b81) L_(b81) 1348 L_(a374) L_(b81) L_(b81) 1349 L_(a375) L_(b81) L_(b81) 1350 L_(a376) L_(b81) L_(b81) 1351 L_(a377) L_(b81) L_(b81) 1352 L_(a378) L_(b81) L_(b81) 1353 L_(a379) L_(b81) L_(b81) 1354 L_(a380) L_(b81) L_(b81) 1355 L_(a381) L_(b81) L_(b81) 1356 L_(a382) L_(b81) L_(b81) 1357 L_(a383) L_(b81) L_(b81) 1358 L_(a384) L_(b81) L_(b81) 1359 L_(a385) L_(b81) L_(b81) 1360 L_(a386) L_(b81) L_(b81) 1361 L_(a387) L_(b81) L_(b81) 1362 L_(a388) L_(b81) L_(b81) 1363 L_(a389) L_(b81) L_(b81) 1364 L_(a390) L_(b81) L_(b81) 1365 L_(a391) L_(b81) L_(b81) 1366 L_(a392) L_(b81) L_(b81) 1367 L_(a393) L_(b81) L_(b81) 1368 L_(a394) L_(b81) L_(b81) 1369 L_(a395) L_(b81) L_(b81) 1370 L_(a396) L_(b81) L_(b81) 1371 L_(a397) L_(b81) L_(b81) 1372 L_(a398) L_(b81) L_(b81) 1373 L_(a399) L_(b81) L_(b81) 1374 L_(a400) L_(b81) L_(b81) 1375 L_(a401) L_(b81) L_(b81) 1376 L_(a402) L_(b81) L_(b81) 1377 L_(a403) L_(b81) L_(b81) 1378 L_(a404) L_(b81) L_(b81) 1379 L_(a405) L_(b81) L_(b81) 1380 L_(a406) L_(b81) L_(b81) 1381 L_(a407) L_(b81) L_(b81) 1382 L_(a408) L_(b81) L_(b81) 1383 L_(a409) L_(b81) L_(b81) 1384 L_(a410) L_(b81) L_(b81) 1385 L_(a411) L_(b81) L_(b81) 1386 L_(a412) L_(b81) L_(b81) 1387 L_(a413) L_(b81) L_(b81) 1388 L_(a414) L_(b81) L_(b81) 1389 L_(a415) L_(b81) L_(b81) 1390 L_(a416) L_(b81) L_(b81) 1391 L_(a417) L_(b81) L_(b81) 1392 L_(a418) L_(b81) L_(b81) 1393 L_(a419) L_(b81) L_(b81) 1394 L_(a420) L_(b81) L_(b81) 1395 L_(a421) L_(b81) L_(b81) 1396 L_(a422) L_(b81) L_(b81) 1397 L_(a423) L_(b81) L_(b81) 1398 L_(a424) L_(b81) L_(b81) 1399 L_(a425) L_(b81) L_(b81) 1400 L_(a426) L_(b81) L_(b81) 1401 L_(a427) L_(b81) L_(b81) 1402 L_(a428) L_(b81) L_(b81) 1403 L_(a429) L_(b81) L_(b81) 1404 L_(a430) L_(b81) L_(b81) 1405 L_(a431) L_(b81) L_(b81) 1406 L_(a432) L_(b81) L_(b81) 1407 L_(a433) L_(b81) L_(b81) 1408 L_(a434) L_(b81) L_(b81) 1409 L_(a435) L_(b81) L_(b81) 1410 L_(a436) L_(b81) L_(b81) 1411 L_(a437) L_(b81) L_(b81) 1412 L_(a438) L_(b81) L_(b81) 1413 L_(a439) L_(b81) L_(b81) 1414 L_(a440) L_(b81) L_(b81) 1415 L_(a441) L_(b81) L_(b81) 1416 L_(a442) L_(b81) L_(b81) 1417 L_(a443) L_(b81) L_(b81) 1418 L_(a444) L_(b81) L_(b81) 1419 L_(a445) L_(b81) L_(b81) 1420 L_(a446) L_(b81) L_(b81) 1421 L_(a447) L_(b81) L_(b81) 1422 L_(a448) L_(b81) L_(b81) 1423 L_(a449) L_(b81) L_(b81) 1424 L_(a450) L_(b81) L_(b81) 1425 L_(a451) L_(b81) L_(b81) 1426 L_(a452) L_(b81) L_(b81) 1427 L_(a453) L_(b81) L_(b81) 1428 L_(a454) L_(b81) L_(b81) 1429 L_(a455) L_(b81) L_(b81) 1430 L_(a456) L_(b81) L_(b81) 1431 L_(a457) L_(b81) L_(b81) 1432 L_(a458) L_(b81) L_(b81) 1433 L_(a459) L_(b81) L_(b81) 1434 L_(a460) L_(b81) L_(b81) 1435 L_(a496) L_(b81) L_(b81) 1436 L_(a500) L_(b81) L_(b81) 1437 L_(a502) L_(b81) L_(b81) 1438 L_(a504) L_(b81) L_(b81) 1439 L_(a508) L_(b81) L_(b81) 1440 L_(a509) L_(b81) L_(b81) 1441 L_(a510) L_(b81) L_(b81) 1442 L_(a515) L_(b81) L_(b81) 1443 L_(a522) L_(b81) L_(b81) 1444 L_(a523) L_(b81) L_(b81) 1445 L_(a524) L_(b81) L_(b81) 1446 L_(a525) L_(b81) L_(b81) 1447 L_(a534) L_(b81) L_(b81) 1448 L_(a535) L_(b81) L_(b81) 1449 L_(a567) L_(b81) L_(b81) 1450 L_(a570) L_(b81) L_(b81) 1451 L_(a583) L_(b81) L_(b81) 1452 L_(a585) L_(b81) L_(b81) 1453 L_(a586) L_(b81) L_(b81) 1454 L_(a689) L_(b81) L_(b81) 1455 L_(a698) L_(b81) L_(b81) 1456 L_(a700) L_(b81) L_(b81) 1457 L_(a1) L_(b1) L_(b3) 1458 L_(a1) L_(b1) L_(b8) 1459 L_(a1) L_(b1) L_(b12) 1460 L_(a1) L_(b1) L_(b17) 1461 L_(a1) L_(b1) L_(b81) 1462 L_(a1) L_(b1) L_(b89) 1463 L_(a1) L_(b3) L_(b12) 1464 L_(a1) L_(b3) L_(b89) 1465 L_(a54) L_(b1) L_(b3) 1466 L_(a54) L_(b1) L_(b8) 1467 L_(a54) L_(b1) L_(b12) 1468 L_(a54) L_(b1) L_(b17) 1469 L_(a54) L_(b1) L_(b81) 1470 L_(a54) L_(b1) L_(b89) 1471 L_(a54) L_(b3) L_(b12) 1472 L_(a54) L_(b3) L_(b89) 1473 L_(a218) L_(b1) L_(b3) 1474 L_(a218) L_(b1) L_(b8) 1475 L_(a218) L_(b1) L_(b12) 1476 L_(a218) L_(b1) L_(b17) 1477 L_(a218) L_(b1) L_(b81) 1478 L_(a218) L_(b1) L_(b89) 1479 L_(a218) L_(b3) L_(b12) 1480 L_(a218) L_(b3) L_(b89) 1481 L_(a243) L_(b1) L_(b3) 1482 L_(a243) L_(b1) L_(b8) 1483 L_(a243) L_(b1) L_(b12) 1484 L_(a243) L_(b1) L_(b17) 1485 L_(a243) L_(b1) L_(b81) 1486 L_(a243) L_(b1) L_(b89) 1487 L_(a243) L_(b3) L_(b12) 1488 L_(a243) L_(b3) L_(b89);

Metal Complex 1489 to Metal Complex 1530 each have a structure of Ir(L_(a))₂L_(c), wherein the two L_(a) are the same or different, and the two L_(a) and L_(c) respectively correspond to the structures listed in the following table: Metal Metal Complex L_(a) L_(a) L_(c) Complex L_(a) L_(a) L_(c) 1489 L_(a462) L_(a462) L_(c1) 1490 L_(a463) L_(a463) L_(c1) 1491 L_(a464) L_(a464) L_(c1) 1492 L_(a465) L_(a465) L_(c1) 1493 L_(a466) L_(a466) L_(c1) 1494 L_(a467) L_(a467) L_(c1) 1495 L_(a468) L_(a468) L_(c1) 1496 L_(a469) L_(a469) L_(c1) 1497 L_(a470) L_(a470) L_(c1) 1498 L_(a471) L_(a471) L_(c1) 1499 L_(a472) L_(a472) L_(c31) 1500 L_(a473) L_(a473) L_(c31) 1501 L_(a474) L_(a474) L_(c31) 1502 L_(a475) L_(a475) L_(c31) 1503 L_(a476) L_(a476) L_(c31) 1504 L_(a477) L_(a477) L_(c31) 1505 L_(a478) L_(a478) L_(c31) 1506 L_(a479) L_(a479) L_(c31) 1507 L_(a480) L_(a480) L_(c31) 1508 L_(a481) L_(a481) L_(c31) 1509 L_(a482) L_(a482) L_(c31) 1510 L_(a483) L_(a483) L_(c31) 1511 L_(a484) L_(a484) L_(c31) 1512 L_(a485) L_(a485) L_(c31) 1513 L_(a486) L_(a486) L_(c31) 1514 L_(a487) L_(a487) L_(c31) 1515 L_(a488) L_(a488) L_(c31) 1516 L_(a489) L_(a489) L_(c31) 1517 L_(a490) L_(a490) L_(c31) 1518 L_(a491) L_(a491) L_(c31) 1519 L_(a492) L_(a492) L_(c31) 1520 L_(a493) L_(a493) L_(c31) 1521 L_(a494) L_(a494) L_(c31) 1522 L_(a495) L_(a495) L_(c31) 1523 L_(a462) L_(a463) L_(c31) 1524 L_(a462) L_(a464) L_(c31) 1525 L_(a462) L_(a465) L_(c31) 1526 L_(a462) L_(a466) L_(c31) 1527 L_(a462) L_(a467) L_(c31) 1528 L_(a462) L_(a468) L_(c31) 1529 L_(a462) L_(a469) L_(c31) 1530 L_(a462) L_(a470) L_(c31);

Metal Complex 1531 to Metal Complex 1554 each have a structure of Ir(L_(a))(L_(b))(L_(c)), wherein L_(a), L_(b) and L_(c) respectively correspond to the structures listed in the following table: Metal Metal Complex L_(a) L_(b) L_(c) Complex L_(a) L_(b) L_(c) 1531 L_(a1) L_(b1) L_(c31) 1532 L_(a1) L_(b3) L_(c31) 1533 L_(a1) L_(b12) L_(c31) 1534 L_(a1) L_(b15) L_(c31) 1535 L_(a1) L_(b17) L_(c31) 1536 L_(a1) L_(b81) L_(c31) 1537 L_(a1) L_(b85) L_(c31) 1538 L_(a1) L_(b90) L_(c31) 1539 L_(a218) L_(b1) L_(c31) 1540 L_(a218) L_(b3) L_(c31) 1541 L_(a218) L_(b12) L_(c31) 1542 L_(a218) L_(b15) L_(c31) 1543 L_(a218) L_(b17) L_(c31) 1544 L_(a218) L_(b81) L_(c31) 1545 L_(a218) L_(b85) L_(c31) 1546 L_(a218) L_(b90) L_(c31) 1547 L_(a463) L_(b1) L_(c31) 1548 L_(a463) L_(b3) L_(c31) 1549 L_(a463) L_(b12) L_(c31) 1550 L_(a463) L_(b15) L_(c31) 1551 L_(a463) L_(b7) L_(c31) 1552 L_(a463) L_(b81) L_(c31) 1553 L_(a463) L_(b85) L_(c31) 1554 L_(a463) L_(b90) L_(c31);

Metal Complex 1555 to Metal Complex 1578 each have a structure of Ir(L_(a))₃, wherein the three L_(a) are the same or different, and the three L_(a) respectively correspond to the structures listed in the following table: Metal Metal Complex L_(a) L_(a) L_(a) Complex L_(a) L_(a) L_(a) 1555 L_(a1) L_(a1) L_(a1) 1556 L_(a54) L_(a54) L_(a54) 1557 L_(a218) L_(a218) L_(a218) 1558 L_(a230) L_(a230) L_(a230) 1559 L_(a243) L_(a243) L_(a243) 1560 L_(a155) L_(a155) L_(a155) 1561 L_(a313) L_(a313) L_(a313) 1562 L_(a254) L_(a254) L_(a254) 1563 L_(a171) L_(a171) L_(a171) 1564 L_(a465) L_(a465) L_(a465) 1565 L_(a1) L_(a3) L_(a4) 1566 L_(a1) L_(a3) L_(a6) 1567 L_(a1) L_(a3) L_(a10) 1568 L_(a1) L_(a3) L_(a13) 1569 L_(a1) L_(a3) L_(a25) 1570 L_(a1) L_(a3) L_(a28) 1571 L_(a1) L_(a3) L_(a35) 1572 L_(a1) L_(a3) L_(a37) 1573 L_(a1) L_(a3) L_(a40) 1574 L_(a1) L_(a3) L_(a42) 1575 L_(a1) L_(a3) L_(a45) 1576 L_(a1) L_(a3) L_(a65) 1577 L_(a1) L_(a3) L_(a80) 1578 L_(a1) L_(a3) L_(a88).


18. An electroluminescent device, comprising: an anode, a cathode, and an organic layer disposed between the anode and the cathode, wherein the organic layer comprises the metal complex of claim
 1. 19. The electroluminescent device of claim 18, wherein the organic layer comprising the metal complex is a light-emitting layer.
 20. The electroluminescent device of claim 19, wherein the electroluminescent device emits green light or white light.
 21. The electroluminescent device of claim 19, wherein the light-emitting layer comprises a first host compound; preferably, the light-emitting layer further comprises a second host compound; more preferably, the first host compound and/or the second host compound comprise at least one chemical group selected from the group consisting of: benzene, pyridine, pyrimidine, triazine, carbazole, azacarbazole, indolocarbazole, dibenzothiophene, aza-dibenzothiophene, dibenzofuran, azadibenzofuran, dibenzoselenophene, triphenylene, azatriphenylene, fluorene, silafluorene, naphthalene, quinoline, isoquinoline, quinazoline, quinoxaline, phenanthrene, azaphenanthrene and combinations thereof.
 22. The electroluminescent device of claim 21, wherein the first host compound has a structure represented by Formula 4:

wherein E₁ to E₆ are, at each occurrence identically or differently, selected from C, CR_(e) or N, at least two of E₁ to E₆ are N, and at least one of E₁ to E₆ is C and joined to Formula A;

wherein Q is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, N, NR′″, CR′″R′″, SiR′″R′″, GeR′″R′″ and R′″C═CR′″; when two R′″ are present at the same time, the two R′″ may be the same or different; p is 0 or 1; r is 0 or 1; when Q is selected from N, p is 0 and r is 1; when Q is selected from the group consisting of O, S, Se, NR′″, CR′″R′″, SiR′″R′″, GeR′″R′″ and R′″C═CR′″, p is 1 and r is 0; L is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 20 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 20 carbon atoms or a combination thereof; Q₁ to Q₈ are, at each occurrence identically or differently, selected from C, CR_(q) or N; R_(e), R′″ and R_(q) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; “*” represents a position where Formula A is joined to Formula 4; and adjacent substituents R_(e), R′″, R_(q) can be optionally joined to form a ring.
 23. The electroluminescent device of claim 22, wherein the first host compound is selected from the group consisting of:


24. The electroluminescent device of claim 21, wherein the second host compound has a structure represented by Formula 5:

wherein L_(x) is, at each occurrence identically or differently, selected from a single bond, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkylene having 3 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 20 carbon atoms, substituted or unsubstituted heteroarylene having 3 to 20 carbon atoms or a combination thereof; V is, at each occurrence identically or differently, selected from C, CR_(v) or N, and at least one of V is C and joined to L_(x); U is, at each occurrence identically or differently, selected from C, CR_(u) or N, and at least one of U is C and joined to L_(x); R_(v) and R_(u) are, at each occurrence identically or differently, selected from the group consisting of: hydrogen, deuterium, halogen, substituted or unsubstituted alkyl having 1 to 20 carbon atoms, substituted or unsubstituted cycloalkyl having 3 to 20 ring carbon atoms, substituted or unsubstituted heteroalkyl having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring atoms, substituted or unsubstituted arylalkyl having 7 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 20 carbon atoms, substituted or unsubstituted aryloxy having 6 to 30 carbon atoms, substituted or unsubstituted alkenyl having 2 to 20 carbon atoms, substituted or unsubstituted alkynyl having 2 to 20 carbon atoms, substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms, substituted or unsubstituted alkylsilyl having 3 to 20 carbon atoms, substituted or unsubstituted arylsilyl having 6 to 20 carbon atoms, substituted or unsubstituted alkylgermanyl having 3 to 20 carbon atoms, substituted or unsubstituted arylgermanyl having 6 to 20 carbon atoms, substituted or unsubstituted amino having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, a hydroxyl group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group and combinations thereof; Ar₆ is, at each occurrence identically or differently, selected from substituted or unsubstituted aryl having 6 to 30 carbon atoms, substituted or unsubstituted heteroaryl having 3 to 30 carbon atoms or a combination thereof; and adjacent substituents R_(v) and R_(u) can be optionally joined to form a ring; preferably, the second host compound has a structure represented by one of Formula 5-a to Formula 5-j:


25. The electroluminescent device of claim 24, wherein the second host compound is selected from the group consisting of:


26. The electroluminescent device of claim 21, wherein the metal complex is doped in the first host compound and the second host compound, and a weight of the metal complex accounts for 1% to 30% of a total weight of the light-emitting layer; preferably, the weight of the metal complex accounts for 3% to 13% of the total weight of the light-emitting layer.
 27. A compound combination, comprising the metal complex of claim
 1. 